Free, publicly-accessible full text available March 18, 2025
- Home
- Search Results
- Page 1 of 1
Search for: All records
Creators/Authors contains:
"Samudrala, Kavyasripriya K"
-
Total Resources3
- Resource Type
-
00000030000
- More
- Availability
-
21
- Author / Contributor
- Filter by Author / Creator
-
-
Conley, Matthew P. (2)
-
Dorn, Rick W. (2)
-
Huynh, Winn (2)
-
Rossini, Aaron J. (2)
-
Samudrala, Kavyasripriya K. (2)
-
Akram, Manjur O (1)
-
Conley, Matthew P (1)
-
Dutton, Jason L (1)
-
Martin, Caleb D (1)
-
Samudrala, Kavyasripriya K (1)
-
#Tyler Phillips, Kenneth E. (0)
-
#Willis, Ciara (0)
-
& Abreu-Ramos, E. D. (0)
-
& Abramson, C. I. (0)
-
& Abreu-Ramos, E. D. (0)
-
& Adams, S.G. (0)
-
& Ahmed, K. (0)
-
& Ahmed, Khadija. (0)
-
& Aina, D.K. Jr. (0)
-
& Akcil-Okan, O. (0)
-
- Filter by Editor
-
-
& Spizer, S. M. (0)
-
& . Spizer, S. (0)
-
& Ahn, J. (0)
-
& Bateiha, S. (0)
-
& Bosch, N. (0)
-
& Brennan K. (0)
-
& Brennan, K. (0)
-
& Chen, B. (0)
-
& Chen, Bodong (0)
-
& Drown, S. (0)
-
& Ferretti, F. (0)
-
& Higgins, A. (0)
-
& J. Peters (0)
-
& Kali, Y. (0)
-
& Ruiz-Arias, P.M. (0)
-
& S. Spitzer (0)
-
& Sahin. I. (0)
-
& Spitzer, S. (0)
-
& Spitzer, S.M. (0)
-
(submitted - in Review for IEEE ICASSP-2024) (0)
-
-
Have feedback or suggestions for a way to improve these results?
!
Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
-
Samudrala, Kavyasripriya K. ; Huynh, Winn ; Dorn, Rick W. ; Rossini, Aaron J. ; Conley, Matthew P. ( , Angewandte Chemie)more » « less
Abstract Al(OC(CF3)3)(PhF) reacts with silanols present on partially dehydroxylated silica to form well‐defined ≡SiOAl(OC(CF3)3)2(O(Si≡)2) (
1 ).27Al NMR and DFT calculations with a small cluster model to approximate the silica surface show that the aluminum in1 adopts a distorted trigonal bipyramidal coordination geometry by coordinating to a nearby siloxane bridge and a fluorine from the alkoxide. Fluoride ion affinity (FIA) calculations follow experimental trends and show that1 is a stronger Lewis acid than B(C6F5)3and Al(OC(CF3)3)(PhF) but is weaker than Al(OC(CF3)3) andiPr3Si+. Cp2Zr(CH3)2reacts with1 to form [Cp2ZrCH3][≡SiOAl(OC(CF3)3)2(CH3)] (3 ) by methide abstraction. This reactivity pattern is similar to reactions of organometallics with the proposed strong Lewis acid sites present on Al2O3. -
Samudrala, Kavyasripriya K. ; Huynh, Winn ; Dorn, Rick W. ; Rossini, Aaron J. ; Conley, Matthew P. ( , Angewandte Chemie International Edition)more » « less
Abstract Al(OC(CF3)3)(PhF) reacts with silanols present on partially dehydroxylated silica to form well‐defined ≡SiOAl(OC(CF3)3)2(O(Si≡)2) (
1 ).27Al NMR and DFT calculations with a small cluster model to approximate the silica surface show that the aluminum in1 adopts a distorted trigonal bipyramidal coordination geometry by coordinating to a nearby siloxane bridge and a fluorine from the alkoxide. Fluoride ion affinity (FIA) calculations follow experimental trends and show that1 is a stronger Lewis acid than B(C6F5)3and Al(OC(CF3)3)(PhF) but is weaker than Al(OC(CF3)3) andiPr3Si+. Cp2Zr(CH3)2reacts with1 to form [Cp2ZrCH3][≡SiOAl(OC(CF3)3)2(CH3)] (3 ) by methide abstraction. This reactivity pattern is similar to reactions of organometallics with the proposed strong Lewis acid sites present on Al2O3.
