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In 2019/2020, Australia experienced its largest wildfire season on record. Smoke covered hundreds of square kilometers across the southeastern coast and reached the site of the 2020 COALA (Characterizing Organics and Aerosol Loading over Australia) field campaign in New South Wales. Using a subset of nighttime observations made by a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS), we calculate emission ratios (ERs) and factors (EFs) for 21 volatile organic compounds (VOCs). We restrict our analysis to VOCs with sufficiently high lifetimes to be minimally impacted by oxidation over the ~8 h between when the smoke was emitted and when it arrived at the field site. We use oxidized VOC to VOC ratios to assess the total amount of radical oxidation: maleic anhydride/furan to assess OH oxidation, and (cis-2-butenediol + furanone)/furan to assess NO3 oxidation. We compare ERs calculated from the freshest portion of the plume to ERs calculated using the entire nighttime period. Finding good agreement between the two, we are able to extend our analysis to VOCs measured in more chemically aged portions of the plume. Our analysis provides ERs and EFs for 9 compounds not previously reported for temperate forests in Australia: acrolein, pentanones/methylbutanal, methyl propanoate, methyl methacrylate, propene, maleic anhydride, benzaldehyde, methyl guaiacol, and methylbenzoic acid. We compare our results with two studies in similar Australian biomes, and two studies focused on US temperate forests. We find mixed agreement for EFs presented from previous studies of Australian wildfires, and generally good agreement with studies focused on fires in the Western US. This suggests that comprehensive field measurements of biomass burning VOC emissions in other regions may be applicable to Australian temperate forests. 

Software system security gets a lot of attention from the industry for its crucial role in protecting private resources. Typically, users access a system’s services via an application programming interface (API). This API must be protected to prevent unauthorized access. One way that developers deal with this challenge is by using role-based access control where each entry point is associated with a set of user roles. However, entry points may use the same methods from lower layers in the application with inconsistent permissions. Currently, developers use integration or penetration testing which demands a lot of effort to test authorization inconsistencies. This paper proposes an automated method to test role-based access control in enterprise applications. Our method verifies inconsistencies within the application using authorization role definitions that are associated with the API entry points. By analyzing the method calls and entity accesses on subsequent layers, inconsistencies across the entire application can be extracted. We demonstrate our solution in a case study and discuss our preliminary results.