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  1. Abstract

    A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a0charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO2+xsamples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO2. The 3a0superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO2highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors.

     
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    Free, publicly-accessible full text available April 1, 2025