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The direct selective laser sintering (SLS) process was successfully demonstrated for additive manufacturing of high-entropy carbide ceramics (HECC), in which a Yb fiber laser was employed for ultrafast (in seconds) reactive sintering of HECC specimens from a powder mixture of constitute monocarbides. A single-phase non-equiatomic HECC was successfully formed in the 4-HECC specimen with a uniform distribution of Zr, Nb, Hf, Ta, and C. In contrast, a three-layer microstructure was formed in the 5-HECC specimen with five metal elements (Zr, Nb, Hf, Ta and Ti), consisting of a TiC-rich top layer, a Zr–Hf–C enriched intermediate layer, and a non-equiatomic Zr–Ta–Nb–Hf–C HECC layer. Vickers hardness of 4- and 5-HECC specimens were 22.2 and 21.8 GPa, respectively, on the surface. These findings have important implications on the fundamental mechanisms governing interactions between laser and monocarbide powders to form a solid solution of HECCs during SLS.

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