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Titanium (Ti) typically exhibits low mobility in geologic fluids due to the low aqueous solubility of common (Fe-)Ti oxide minerals. Consequently, Ti isotope variations (δ49/47Ti, given as δ49Ti) in geologic systems are primarily attributed to magmatic differentiation. Thus, the potential for fluid-mineral fractionation has received less attention. However, ligand-rich fluids are capable of mobilizing Ti as observed in natural systems and laboratory studies. As hydrothermal ore mineralization is commonly associated with ligand-rich brines capable of transporting significant quantities of metals, Ti isotopes may aid in understanding mineralization and alteration in complex hydrothermal systems. Here we present data from computational modeling of various Ti coordination complexes theorized to exist in geologic systems and/or under relevant experimental conditions as well as computed fractionation factors for various Ti-bearing crystalline phases to investigate the basic mechanics of equilibrium fluid-mineral Ti isotope fractionation. These results indicate that equilibrium fluid-mineral Ti isotope exchange between our modeled Ti complexes and phases with 6-coordinated Ti is predicted to generally lead to enrichment of heavy Ti isotopes in the fluid. Because minerals with 6-coordinated Ti (such as magnetite and ilmenite) are the most important reservoirs of Ti in the solid Earth, Ti isotope equilibration between terrestrial rocks and fluids can be generalized to enrich the fluid in heavy Ti isotopes. We also performed magnetite-ülvospinel leaching experiments to investigate fluid-mineral Ti isotope fractionation in this phase. Mineral leaching experiments varying acid strength, leaching temperature, and reaction time with HCl and HF qualitatively support the prediction that the fluid phase will become enriched in heavy Ti isotopes during fluid-mineral interactions that approach equilibrium with Ti-rich magnetite. Additionally, the leaching data also suggest that the fluid becomes slightly enriched in lighter Ti isotopes when Ti exchange is limited—potentially due to kinetic effects. Therefore, magnetite from natural systems may be depleted in heavy Ti isotopes during regenerative mineral replacement involving equilibration with fluids or may possibly become depleted in light Ti isotopes under a kinetic fractionation regime—leading to mineral δ49Ti values that are insufficiently explained by magmatic differentiation or inter-mineral fractionation. These results are a first look at fluid-mineral interactions that may affect Ti isotope fractionation in hydrothermal mineral systems, and Ti isotopes should be further studied as a potential method of understanding aqueous metal transport and tracing alteration in mineral deposits. 

Abstract We investigate the cold and warm gas content, kinematics, and spatial distribution of six local massive elliptical galaxies to probe the origin of the multiphase gas in their atmospheres. We report new observations, including Stratospheric Observatory for Infrared Astronomy [C ii ], Atacama Large Millimeter/submillimeter Array CO, Multi Unit Spectroscopic Explorer (MUSE) H α +[N ii ], and Very Large Array (VLA) radio observations. These are complemented by a large suite of multiwavelength archival data sets, including thermodynamical properties of the hot gas and radio jets, which are leveraged to investigate the role of active galactic nucleus (AGN) feeding/feedback in regulating the multiphase gas content. Our galactic sample shows a significant diversity in cool gas content, spanning filamentary and rotating structures. In our noncentral galaxies, the distribution of such gas is often concentrated, at variance with the more extended features observed in central galaxies. Misalignment between the multiphase gas and stars suggest that stellar mass loss is not the primary driver. A fraction of the cool gas might be acquired via galaxy interactions, but we do not find quantitative evidence of mergers in most of our systems. Instead, key evidence supports the origin via condensation out of the diffuse halo. Comparing with chaotic cold accretion (CCA) simulations, we find that our cool gas-free galaxies are likely in the overheated phase of the self-regulated AGN cycle, while for our galaxies with cool gas, the k-plot and AGN power correlation corroborate the phase of CCA feeding in which the condensation rain is triggering more vigorous AGN heating. The related C-ratio further shows that central/noncentral galaxies are expected to generate an extended/inner rain, consistent with our sample. 

Abstract X-ray bursts are among the brightest stellar objects frequently observed in the sky by space-based telescopes. A type-I X-ray burst is understood as a violent thermonuclear explosion on the surface of a neutron star, accreting matter from a companion star in a binary system. The bursts are powered by a nuclear reaction sequence known as the rapid proton capture process (rp process), which involves hundreds of exotic neutron-deficient nuclides. At so-called waiting-point nuclides, the process stalls until a slower β + decay enables a bypass. One of the handful of rp process waiting-point nuclides is 64 Ge, which plays a decisive role in matter flow and therefore the produced X-ray flux. Here we report precision measurements of the masses of 63 Ge, 64,65 As and 66,67 Se—the relevant nuclear masses around the waiting-point 64 Ge—and use them as inputs for X-ray burst model calculations. We obtain the X-ray burst light curve to constrain the neutron-star compactness, and suggest that the distance to the X-ray burster GS 1826–24 needs to be increased by about 6.5% to match astronomical observations. The nucleosynthesis results affect the thermal structure of accreting neutron stars, which will subsequently modify the calculations of associated observables. 

Ascospores generated during sexual reproduction are the primary inoculum for the wheat scab fungus Fusarium graminearum. Purine metabolism is known to play important roles in fungal pathogens but its lifecycle stage-specific regulation is unclear. By characterizing the genes involved in purine de novo and salvage biosynthesis pathways, we showed that de novo syntheses of inosine, adenosine and guanosine monophosphates (IMP, AMP and GMP) are important for vegetative growth, sexual/asexual reproduction, and infectious growth, whereas purine salvage synthesis is dispensable for these stages in F. graminearum. Addition of GMP rescued the defects of the Fgimd1 mutant in vegetative growth and conidiation but not sexual reproduction, whereas addition of AMP rescued all of these defects of the Fgade12 mutant, suggesting that the function of de novo synthesis of GMP rather than AMP is distinct in sexual stages. Moreover, Acd1, an ortholog of AMP deaminase, is dispensable for growth but essential for ascosporogenesis and pathogenesis, suggesting that AMP catabolism has stage-specific functions during sexual reproduction and infectious growth. The expression of almost all the genes involved in de novo purine synthesis is downregulated during sexual reproduction and infectious growth relative to vegetative growth. This study revealed that F. graminearum has stage-specific regulation of purine metabolism during infectious growth and sexual reproduction. 

This proceeding was published in a special issue of J. Laser Appl. as: H. Cheng, C. Xia, S. M. Kuebler, P. Golvari, M. Sun, M. Zhang, X. Yu*. "Generation of Bessel-beam arrays for parallel fabrication in two-photon polymerization." J. Laser Appl. 2021, 33, 012040-1 - 012040-6; https://doi.org/10.2351/7.0000313. 

The Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE) is a blind narrow-band H α + [NII] imaging survey of the Virgo cluster carried out with MegaCam at the Canada-French-Hawaii telescope. We use a new set of data extracted from VESTIGE to study the impact of the hostile cluster environment on the star formation process down to the scale of HII regions (∼50 pc). Here, HII regions are identified and their parameters measured using the HII PHOT code on a sample of 114 late-type galaxies spanning a wide range in morphological type (Sa-Sd, Im, BCD), stellar mass (10 6.5  ≤  M star  ≤ 10 11 M ⊙ ), and star formation activity (10 −3  ≤ SFR ≤ 10 M ⊙ yr −1 ). Owing to the exquisite average resolution of the VESTIGE data (0.65 arcsec), we detect 11302 HII regions with an H α luminosity L (H α ) ≥ 10 37 erg s −1 . We show that the typical number of HII regions in gas-stripped objects is significantly lower than in healthy late-types of similar stellar mass. We also show that in these gas-stripped galaxies the number of HII regions significantly drops outside the effective radius, suggesting that the quenching process occurs outside-in, in agreement with other multifrequency observations. These new results consistently confirm that the main mechanism responsible for the decrease of the star formation activity observed in cluster galaxies is ram pressure, allowing us to discard other milder processes such as starvation or strangulation, which are unable to reproduce the observed radially truncated profiles.