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Creators/Authors contains: "Swan, James W."

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  1. ; ; ; ; ; (, Proceedings of the National Academy of Sciences)
    Electrical transport in semiconducting and metallic particle suspensions is an enabling feature of emerging grid-scale battery technologies. Although the physics of the transport process plays a key role in these technologies, no universal framework has yet emerged. Here, we examine the important contribution of shear flow to the electrical transport of non-Brownian suspensions. We find that these suspensions exhibit a strong dependence of the transport rate on the particle volume fraction and applied shear rate, which enables the conductivity to be dynamically changed by over 10 7 decades based on the applied shear rate. We combine experiments and simulations to conclude that the transport process relies on a combination of charge and particle diffusion with a rate that can be predicted using a quantitative physical model that incorporates the self-diffusion of the particles. 
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  2. ; ; (, AIChE Journal)
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  3. ; ; ; (, Langmuir)
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  4. ; ; ; ; ; ; ; ; ; ; et al (, The Journal of Chemical Physics)