Search for: All records

Exploiting the interplay of anisotropic diamagnetic susceptibility of liquid crystalline monomers and site selective photopolymerization enables the fabrication of 3D freeforms with highly refined microstructures. 

The effect of chain extender structure and composition on the thermomechanical properties of liquid crystal elastomers (LCE) synthesized using thiol-acrylate Michael addition is presented. The intrinsic molecular stiffness of the thiol chain extender and its relative molar ratio to acrylate-based host mesogens determine the magnitudes of the thermomechanical strains, temperatures at which they are realized and the mechanical work-content. A non-linear structure-property relationship emerges, wherein higher concentrations of flexible extenders first magnify the thermomechanical sensitivity, but a continued increase leads to weaker actuation. Understanding this interplay leads to a composite material platform, enabling a peak specific work production of ~2 J/kg using ~115 mW of electrical power supplied at 2 V. Composites of LCE with eGaIn liquid metal (LM) are prepared, which act as heaters, while being capable of actuation themselves. The thermomechanically active electrodes convert the electrical power into Joule heat, which they efficiently couple with the neat LCE to which they are bound. This system harnesses the nascent responsiveness of the LCE using electrodes that work with them, instead of fighting against them (or passively standing in the way). Specific work generated increases when subjected to increasing levels of load, reaching a peak at loads 260x the actuator weight. These ideas are extended to tri-layered actuators, where LCE films with orthogonal molecular orientations sandwich LCE-LM composite heaters. Torsional actuation modes are harnessed to twist under load. 

Abstract Transversely curved composite shells of liquid crystal elastomer and polyethylene terephthalate with innervated electrodes present millisecond‐scale actuation with ≈200 mW electrical power inputs at low voltages (≈1 V). The molecular orientation is aligned to direct the thermomechanical work‐content to evert the native curvature. When powered, the curved structure initially remains latent and builds up strain energy. Thereafter, the work content is released in an ms‐scale impulse. The thin‐film actuators are powered against opposing loads to perform up to 10⁻⁵J of work. High speed imaging reveals tip velocities of several 100 mm s⁻¹with powers approaching 10⁻⁴ J s⁻¹. The design eschews bistability. After snap‐through, when the power is off, the actuator spontaneously resets to its native state. The actuation profiles are functions of the geometry and the electrical pulse patterns. The latency of actuation is reduced by powering the actuators with pulses that trigger snap‐through, allow its reset to the native state, but prevent its cooling to the ambient before subsequent actuation cycles. The actuation is harnessed in sub‐gram scale robots, including water‐strider mimicking configurations and steerable robots that can navigate on compliant (sand) and hard (slippery) surfaces. A viable template for impulsive actuation using frugal electrical power emerges.