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Creators/Authors contains: "Tope, Cynthia A."

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  1. Abstract

    Reaction of carbene‐stabilized disilicon (1) with the lithium‐based dithiolene radical (2.) affords the first dianionic silicon tris(dithiolene) complex (3). Notably, the formation of3represents the unprecedented utilization of carbene‐stabilized disilicon (1) as a silicon‐transfer agent. The nature of3was probed by multinuclear NMR spectroscopy, single‐crystal X‐ray diffraction, and DFT computations.

     
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  2. Abstract

    Reaction of carbene‐stabilized disilicon (1) with the lithium‐based dithiolene radical (2.) affords the first dianionic silicon tris(dithiolene) complex (3). Notably, the formation of3represents the unprecedented utilization of carbene‐stabilized disilicon (1) as a silicon‐transfer agent. The nature of3was probed by multinuclear NMR spectroscopy, single‐crystal X‐ray diffraction, and DFT computations.

     
    more » « less