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Creators/Authors contains: "Turro, Claudia"

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  1. ; ; ; (, Inorganic Chemistry)
    Free, publicly-accessible full text available October 28, 2025
  2. ; ; ; (, Inorganic Chemistry)
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  3. ; ; ; ; ; ; (, Inorganic Chemistry)
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  4. ; ; ; (, The Journal of Physical Chemistry A)
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  5. ; ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  6. ; ; ; ; ; (, Inorganic Chemistry)
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  7. ; ; ; ; ; (, Nature Communications)
    Abstract One-photon-absorbing photosensitizers are commonly used in homogeneous photocatalysis which require the absorption of ultraviolet (UV) /visible light to populate the desired excited states with adequate energy and lifetime. Nevertheless, the limited penetration depth and competing absorption by organic substrates of UV/visible light calls upon exploring the utilization of longer-wavelength irradiation, such as near-infrared light (λ irr  > 700 nm). Despite being found applications in photodynamic therapy and bioimaging, two-photon absorption (TPA), the simultaneous absorption of two photons by one molecule, has been rarely explored in homogeneous photocatalysis. Herein, we report a group of ruthenium polypyridyl complexes possessing TPA capability that can drive a variety of organic transformations upon irradiation with 740 nm light. We demonstrate that these TPA ruthenium complexes can operate in an analogous manner as one-photon-absorbing photosensitizers for both energy-transfer and photoredox reactions, as well as function in concert with a transition metal co-catalyst for metallaphotoredox C–C coupling reactions. 
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  8. ; ; ; (, Journal of the American Chemical Society)
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  9. ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  10. ; ; ; ; ; ; ; ; (, Inorganic Chemistry)
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