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Liu, Yue; Dang, Andy; Urban, Jan; Turecek, Frantisek (, Angewandte Chemie)null (Ed.)Adenosine radicals tagged with a fixed-charge group were generated in the gas phase and structurally characterized by tandem mass spectrometry, deuterium labeling, and UV/Vis action spectroscopy. Experimental results in combination with Born–Oppenheimer molecular dynamics, ab initio, and excited-state calculations led to unambiguous assignment of adenosine radicals as N-7 hydrogen atom adducts. The chargetagged radicals were found to be electronically equivalent to natural DNA nucleoside radicals.more » « less
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Korn, Joseph A.; Urban, Jan; Dang, Andy; Nguyen, Huong T.; Tureček, František (, The Journal of Physical Chemistry Letters)
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Wang, Ke; Goldenberg, Amit; Dorison, Charles A.; Miller, Jeremy K.; Uusberg, Andero; Lerner, Jennifer S.; Gross, James J.; Agesin, Bamikole Bamikole; Bernardo, Márcia; Campos, Olatz; et al (, Nature Human Behaviour)
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