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  1. Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of mechanophores that translate mechanical energy into a variety of functional responses ranging from color change to small-molecule release. These productive chemical changes typically occur at the length scale of a few covalent bonds (Å) but require large energy inputs and strains on the micro-to-macro scale in order to achieve even low levels of mechanophore activation. The minimal activation hinders the translation of the available chemical responses into materials and device applications. The mechanophore activation challenge inspires core questions at yet another length scale of chemical control, namely: What are the molecular-scale features of a polymeric material that determine the extent of mechanophore activation? Further, how do we marry advances in the chemistry of polymer networks with the chemistry of mechanophores to create stress-responsive materials that are well suited for an intended application? In this Perspective, we speculate as to the potential match between covalent polymer mechanochemistry and recent advances in polymer network chemistry, specifically, topologically controlled networks and the hierarchical material responses enabled by multi-network architectures and mechanically interlocked polymers. Both fundamental and applied opportunities unique to the union of these two fields are discussed. 
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  2. null (Ed.)
    A one pot synthesis is applied to control the chain structure and architecture of multiply dynamic polymers, enabling fine tuning of materials properties by choice of polymer chain length or crosslink density. Macromolecules containing both non-covalent linkers based on quadruple hydrogen-bonded 2-(((6-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)hexyl)carbamoyl)oxy)ethyl methacrylate (UPyMA), and thermoresponsive dynamic covalent furan–maleimide based Diels–Alder linkers are explored. The primary polymer's architecture was controlled by reversible addition-fragmentation chain transfer (RAFT) polymerization, with the dynamic non-covalent (UPyMA) and dynamic covalent furfuryl methacrylate (FMA) units incorporated into the same backbone. The materials are crosslinked, taking advantage of the “click” chemistry properties of the furan–maleimide reaction. The polymer materials showed stimulus-responsive thermomechanical properties with a decrosslinking temperature increasing with the polymer's primary chain length and crosslink density. The polymers had good thermally promoted self-healing properties due to the dynamic covalent Diels–Alder bonds. Besides, the materials had excellent stress relaxation characteristics induced by the exchange of the hydrogen bonds in UPyMA units. 
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  3. Recent progress on stretchable, tough dual-dynamic polymer single networks (SN) and interpenetrated networks (IPN) has broadened the potential applications of dynamic polymers. However, the impact of macromolecular structure on the material mechanics remains poorly understood. Here, rapidly exchanging hydrogen bonds and thermoresponsive Diels–Alder bonds were included into molecularly engineered interpenetrated network materials. RAFT polymerization was used to make well-defined polymers with control over macromolecular architecture. The IPN materials were assessed by gel permeation chromatography, differential scanning calorimetry, tensile testing and rheology. The mechanical properties of these IPN materials can be tuned by varying the crosslinker content and chain length. All materials are elastic and have dynamic behavior at both ambient temperature and elevated temperature (90 °C), owing to the presence of the dual dynamic noncovalent and covalent bonds. 100% self-healing recovery was achieved and a maximum stress level of up to 6 MPa was obtained. The data suggested the material's healing properties are inversely proportional to the content of the crosslinker or the degree of polymerization at both room and elevated temperature. The thermoresponsive crosslinker restricted deformation to some extent in an ambient environment but gave excellent malleability upon heating. The underlying mechanism was explored by the computational simulations. Furthermore, a single network material with the same crosslinker content and degree of polymerization as the IPN was made. The SN was substantially weaker than the comparable IPN material. 
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