Search for: All records

Abstract. Deposition of sulfuric acid in ice cores is important both for understanding past volcanic activity and for synchronizing ice core timescales. Sulfuric acid has a low eutectic point, so it can potentially exist in liquid at grain boundaries and veins, accelerating chemical diffusion. A high effective diffusivity would allow post-depositional diffusion to obscure the climate history and the peak matching among older portions of ice cores. Here, we use records of sulfate from the European Project of Ice Coring in Antarctica (EPICA) Dome C (EDC) ice core to estimate the effective diffusivity of sulfuric acid in ice. We focus on EDC because multiple glacial–interglacial cycles are preserved, allowing analysis for long timescales and deposition in similar climates. We calculate the mean concentration gradient and the width of prominent volcanic events, and analyze the evolution of each with depth and age. We find the effective diffusivities for interglacial and glacial maximums to be 5±3×10-9 m2 a−1, an order of magnitude lower than a previous estimate derived from the Holocene portion of EDC (Barnes et al., 2003). The effective diffusivity may be even smaller if the bias from artificial smoothing from the sampling is accounted for. Effective diffusivity is not obviously affected by the ice temperature until about −10 ∘C, 3000 m depth, which is also where anomalous sulfate peaks begin to be observed (Traversi et al., 2009). Low effective diffusivity suggests that sulfuric acid is not readily diffusing in liquid-like veins in the upper portions of the Antarctic Ice Sheet and that records may be preserved in deep, old ice if the ice temperature remains well below the pressure melting point. 

Abstract Converting measurements of ice-sheet surface elevation change to mass change requires measurements of accumulation and knowledge of the evolution of the density profile in the firn. Most firn-densification models are tuned using measured depth–density profiles, a method which is based on an assumption that the density profile in the firn is invariant through time. Here we present continuous measurements of firn-compaction rates in 12 boreholes near the South Pole over a 2 year period. To our knowledge, these are the first continuous measurements of firn compaction on the Antarctic plateau. We use the data to derive a new firn-densification algorithm framed as a constitutive relationship. We also compare our measurements to compaction rates predicted by several existing firn-densification models. Results indicate that an activation energy of 60 kJ mol⁻¹, a value within the range used by current models, best predicts the seasonal cycle in compaction rates on the Antarctic plateau. Our results suggest models can predict firn-compaction rates with at best 7% uncertainty and cumulative firn compaction on a 2 year timescale with at best 8% uncertainty. 

Abstract. In 2013 an ice core was recovered from Roosevelt Island, an ice dome between two submarine troughs carved by paleo-ice-streams in the Ross Sea, Antarctica. The ice core is part of the Roosevelt Island Climate Evolution (RICE) project and provides new information about the past configuration of the West Antarctic Ice Sheet (WAIS) and its retreat during the last deglaciation. In this work we present the RICE17 chronology, which establishes the depth–age relationship for the top 754 m of the 763 m core. RICE17 is a composite chronology combining annual layer interpretations for 0–343 m (Winstrup et al., 2019) with new estimates for gas and ice ages based on synchronization of CH4 and δ18Oatm records to corresponding records from the WAIS Divide ice core and by modeling of the gas age–ice age difference. Novel aspects of this work include the following: (1) an automated algorithm for multiproxy stratigraphic synchronization of high-resolution gas records; (2) synchronization using centennial-scale variations in methane for pre-anthropogenic time periods (60–720 m, 1971 CE to 30 ka), a strategy applicable for future ice cores; and (3) the observation of a continuous climate record back to ∼65 ka providing evidence that the Roosevelt Island Ice Dome was a constant feature throughout the last glacial period. 

Abstract. We present a 2700-year annually resolved chronology and snow accumulationhistory for the Roosevelt Island Climate Evolution (RICE) ice core, Ross IceShelf, West Antarctica. The core adds information on past accumulationchanges in an otherwise poorly constrained sector of Antarctica. The timescale was constructed by identifying annual cycles inhigh-resolution impurity records, and it constitutes the top part of theRoosevelt Island Ice Core Chronology 2017 (RICE17). Validation by volcanicand methane matching to the WD2014 chronology from the WAIS Divide ice coreshows that the two timescales are in excellent agreement. In a companionpaper, gas matching to WAIS Divide is used to extend the timescale for thedeeper part of the core in which annual layers cannot be identified. Based on the annually resolved timescale, we produced a record of past snowaccumulation at Roosevelt Island. The accumulation history shows thatRoosevelt Island experienced slightly increasing accumulation rates between700 BCE and 1300 CE, with an average accumulation of 0.25±0.02 mwater equivalent (w.e.) per year. Since 1300 CE, trends in the accumulationrate have been consistently negative, with an acceleration in the rate ofdecline after the mid-17th century. The current accumulation rate atRoosevelt Island is 0.210±0.002 m w.e. yr−1 (average since 1965 CE, ±2σ), and it is rapidly declining with a trend corresponding to0.8 mm yr−2. The decline observed since the mid-1960s is 8 times fasterthan the long-term decreasing trend taking place over the previouscenturies, with decadal mean accumulation rates consistently being belowaverage. Previous research has shown a strong link between Roosevelt Islandaccumulation rates and the location and intensity of the Amundsen Sea Low,which has a significant impact on regional sea-ice extent. The decrease inaccumulation rates at Roosevelt Island may therefore be explained in termsof a recent strengthening of the ASL and the expansion of sea ice in the easternRoss Sea. The start of the rapid decrease in RICE accumulation ratesobserved in 1965 CE may thus mark the onset of significant increases inregional sea-ice extent. 

Abstract. The South Pole Ice Core (SPICEcore) was drilled in 2014–2016 to provide adetailed multi-proxy archive of paleoclimate conditions in East Antarcticaduring the Holocene and late Pleistocene. Interpretation of these recordsrequires an accurate depth–age relationship. Here, we present the SPICEcore (SP19) timescale for the age of the ice of SPICEcore. SP19 is synchronized to theWD2014 chronology from the West Antarctic Ice Sheet Divide (WAIS Divide) icecore using stratigraphic matching of 251 volcanic events. These eventsindicate an age of 54 302±519 BP (years before 1950) at thebottom of SPICEcore. Annual layers identified in sodium and magnesium ionsto 11 341 BP were used to interpolate between stratigraphic volcanic tiepoints, yielding an annually resolved chronology through the Holocene.Estimated timescale uncertainty during the Holocene is less than 18 yearsrelative to WD2014, with the exception of the interval between 1800 to 3100BP when uncertainty estimates reach ±25 years due to widely spacedvolcanic tie points. Prior to the Holocene, uncertainties remain within 124 years relative to WD2014. Results show an average Holocene accumulation rateof 7.4 cm yr−1 (water equivalent). The time variability of accumulation rateis consistent with expectations for steady-state ice flow through the modernspatial pattern of accumulation rate. Time variations in nitrateconcentration, nitrate seasonal amplitude and δ15N of N2 in turn are as expected for the accumulation rate variations. The highlyvariable yet well-constrained Holocene accumulation history at the site canhelp improve scientific understanding of deposition-sensitive climateproxies such as δ15N of N2 and photolyzed chemicalcompounds. 

Abstract Recent observations of increased discharge through fast-flowing outlet glaciers and ice streams motivate questions concerning the inland migration of regions of fast flow, which could increase drawdown of the ice-sheet interior. To investigate one process that could lead to inland migration we conduct experiments with a two-dimensional, full-stress, transient ice-flow model. An initial steady state is perturbed by initiating a jump in sliding speed over a fraction of the model domain. As a result, longitudinal-stress gradients increase frictional melting upstream from the slow-to-fast sliding transition, and a positive feedback between longitudinal-stress gradients, basal meltwater production and basal sliding causes the sliding transition to migrate upstream over time. The distance and speed of migration depend on the magnitude of the perturbation and on the degree of non-linearity assumed in the link between basal stress and basal sliding: larger perturbations and/or higher degrees of non-linearity lead to farther and faster upstream migration. Migration of the sliding transition causes the ice sheet to thin over time and this change in geometry limits the effects of the positive feedback, ultimately serving to impede continued upstream migration. 

High-resolution, well-dated climate archives provide an opportunity to investigate the dynamic interactions of climate patterns relevant for future projections. Here, we present data from a new, annually dated ice core record from the eastern Ross Sea, named the Roosevelt Island Climate Evolution (RICE) ice core. Comparison of this record with climate reanalysis data for the 1979–2012 interval shows that RICE reliably captures temperature and snow precipitation variability in the region. Trends over the past 2700 years in RICE are shown to be distinct from those in West Antarctica and the western Ross Sea captured by other ice cores. For most of this interval, the eastern Ross Sea was warming (or showing isotopic enrichment for other reasons), with increased snow accumulation and perhaps decreased sea ice concentration. However, West Antarctica cooled and the western Ross Sea showed no significant isotope temperature trend. This pattern here is referred to as the Ross Sea Dipole. Notably, during the Little Ice Age, West Antarctica and the western Ross Sea experienced colder than average temperatures, while the eastern Ross Sea underwent a period of warming or increased isotopic enrichment. From the 17th century onwards, this dipole relationship changed. All three regions show current warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea but increasing in the western Ross Sea. We interpret this pattern as reflecting an increase in sea ice in the eastern Ross Sea with perhaps the establishment of a modern Roosevelt Island polynya as a local moisture source for RICE.