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Abstract Magnetic fields are uniquely valuable for creating colloidal nanostructured materials, not only providing a means for controlled synthesis but also guiding their self‐assembly into distinct superstructures. In this study, a magnetothermal process for synthesizing hybrid nanostructures comprising ferrimagnetic magnetite nanorods coated with fluorescent perovskite nanocrystals is reported and their magnetic assembly into superstructures capable of emitting linear and circularly polarized light are demonstrated. Under UV excitation, the superstructures assembled in a liner magnetic field produce linear polarized luminescence, and those assembled in a chiral magnetic field exhibit strong circularly polarized luminescence (CPL) with aglumvalue up to 0.44 (±0.004). The CPL is believed to originate from the dipolar interaction between neighboring perovskite nanocrystals attached to the chiral assemblies and the chiral‐selective absorption of the perovskite emission by the magnetite phase. The magnetic synthesis and assembly approaches and the resulting distinctive chiral superstructures are anticipated to open up new avenues for designing diverse functional chiroptical devices.more » « less
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We demonstrate a thermoreflectance-based thermometry technique with an ultimate temperature resolution of 60 µK in a 2.6 mHz bandwidth. This temperature resolution was achieved using a 532 nm-wavelength probe laser and a ∼1 µm-thick silicon transducer film with a thermoreflectance coefficient of −4.7 × 10−3 K−1at room temperature. The thermoreflectance sensitivity reported here is over an order-of-magnitude greater than that of metal transducers, and is comparable to the sensitivity of traditional resistance thermometers. Supporting calculations reveal that the enhancement in sensitivity is due to optical interference in the thin film.more » « less
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CaF2, BaF2, and MgF2are low-index, infrared-transparent materials that are extensively used in optical systems. Despite their technological importance, a systematic investigation into the temperature dependence of their optical properties is lacking. In this study, spectroscopic ellipsometry was used to obtain the refractive index of monocrystalline CaF2, BaF2, and MgF2for wavelengths between 220 nm and 1700 nm, and for temperatures between 21 °C and 368 °C. The raw ellipsometric data was fit to a Sellmeier model with temperature-dependent oscillator terms to extract the real part of the refractive index of each material. The refractive index of CaF2and BaF2was observed to decrease linearly with increasing temperature, which can be largely attributed to a reduction in the mass density due to thermal expansion. In contrast, the refractive index of MgF2was found to vary nonlinearly with temperature, which suggests competing effects from the material’s electronic polarizability. The temperature-dependent refractive index data reported here provide a finely-resolved mapping of the thermo-optic coefficient for these three materials, which could inform the development of optical devices operating at elevated or unsteady temperatures.more » « less
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