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Abstract Over a hundred gravitational-wave (GW) detections and candidates have been reported from the first three observing runs of the Advanced LIGO-Virgo-KAGRA (LVK) detectors. Among these, the most intriguing events are binary black hole mergers that result in a “lite” intermediate-mass black hole (IMBH) of ∼102M⊙, such as GW170502 and GW190521. In this study, we investigate 11 GW candidates from LVK’s third observing run with total detector-frame masses in the lite IMBH range. Using the Bayesian inference algorithmRIFT, we systematically analyze these candidates with three state-of-the-art waveform models that incorporate higher harmonics, which are crucial for resolving lite IMBHs in LVK data. For each candidate, we infer the premerger and postmerger black hole masses in the source frame, along with black hole spin projections across all three models. Under the assumption that these are binary black hole mergers, our analysis finds that five have a postmerger lite IMBH with masses ranging from 110 to 350M⊙with over 90% confidence interval. Additionally, we note that one of their premerger black holes is within the pair-instability supernova mass gap (60–120M⊙), and two premerger black holes are above the mass gap. Furthermore, we report discrepancies among the three waveform models in intrinsic parameters, with at least three GW candidates showing deviations beyond accepted statistical limits. While the astrophysical certainty of these candidates cannot be established, our study provides a foundation to probe the lite IMBH population that emerge within the low-frequency noise spectrum of LVK detectors.more » « less
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Abstract A budget approach is used to disentangle drivers of the seasonal mixed layer carbon cycle at Station ALOHA (A Long‐term Oligotrophic Habitat Assessment) in the North Pacific Subtropical Gyre (NPSG). The budget utilizes data from the WHOTS (Woods Hole—Hawaii Ocean Time‐series Site) mooring, and the ship‐based Hawai'i Ocean Time‐series (HOT) in the NPSG, a region of significant oceanic carbon uptake. Parsing the carbon variations into process components allows an assessment of both the proportional contributions of mixed layer carbon drivers and the seasonal interplay of drawdown and supply from different processes. Annual net community production reported here is at the lower end of previously published data, while net community calcification estimates are 4‐ to 7‐fold higher than available sediment trap data, the only other estimate of calcium carbonate export at this location. Although the observed seasonal cycle in dissolved inorganic carbon in the NPSG has a relatively small amplitude, larger fluxes offset each other over an average year. Major supply comes from physical transport, especially lateral eddy transport throughout the year and entrainment in the winter, offset by biological carbon uptake in the spring. Gas exchange plays a smaller role, supplying carbon to the surface ocean between Dec‐May and outgassing in Jul‐Oct. Evaporation‐precipitation (E‐P) is variable with precipitation prevailing in the first half and evaporation in the second half of the year. The observed total alkalinity signal is largely governed by E‐P with a somewhat stronger net calcification signal in the wintertime.more » « less
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Abstract There is great interest in improving our understanding of the respective roles of the ocean and atmosphere in variability and change in weather and climate. Due to the sparsity of sustained observing sites in the open ocean, information about the air–sea exchanges of heat, freshwater, and momentum is often drawn from models. In this paper observations from three long-term surface moorings deployed in the trade wind regions of the Pacific and Atlantic Oceans are used to compare observed means and low-passed air–sea fluxes from the moorings with coincident records from three atmospheric reanalyses (ERA5, NCEP-2, and MERRA-2) and from CMIP6 coupled models. To set the stage for the comparison, the methodologies of maintaining the long-term surface moorings, known as ocean reference stations (ORS), and assessing the accuracies of their air–sea fluxes are described first. Biases in the reanalyses’ means and low-passed wind stresses and net air–sea heat fluxes are significantly larger than the observational uncertainties and in some case show variability in time. These reanalyses and most CMIP6 models fail to provide as much heat into the ocean as observed. In the discussion and conclusions section, long-term observing sites in the open ocean are seen as essential, independent benchmarks not only to document the coupling between the atmosphere and ocean but also to promote collaborative efforts to assess and improve the ability of models to simulate air–sea fluxes.more » « less
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Ocean surface radiation measurement best practices have been developed as a first step to support the interoperability of radiation measurements across multiple ocean platforms and between land and ocean networks. This document describes the consensus by a working group of radiation measurement experts from land, ocean, and aircraft communities. The scope was limited to broadband shortwave (solar) and longwave (terrestrial infrared) surface irradiance measurements for quantification of the surface radiation budget. Best practices for spectral measurements for biological purposes like photosynthetically active radiation and ocean color are only mentioned briefly to motivate future interactions between the physical surface flux and biological radiation measurement communities. Topics discussed in these best practices include instrument selection, handling of sensors and installation, data quality monitoring, data processing, and calibration. It is recognized that platform and resource limitations may prohibit incorporating all best practices into all measurements and that spatial coverage is also an important motivator for expanding current networks. Thus, one of the key recommendations is to perform interoperability experiments that can help quantify the uncertainty of different practices and lay the groundwork for a multi-tiered global network with a mix of high-accuracy reference stations and lower-cost platforms and practices that can fill in spatial gaps.more » « less
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Abstract Upper-ocean turbulence is central to the exchanges of heat, momentum, and gasses across the air/sea interface, and therefore plays a large role in weather and climate. Current understanding of upper-ocean mixing is lacking, often leading models to misrepresent mixed-layer depths and sea surface temperature. In part, progress has been limited due to the difficulty of measuring turbulence from fixed moorings which can simultaneously measure surface fluxes and upper-ocean stratification over long time periods. Here we introduce a direct wavenumber method for measuring Turbulent Kinetic Energy (TKE) dissipation rates, ϵ , from long-enduring moorings using pulse-coherent ADCPs. We discuss optimal programming of the ADCPs, a robust mechanical design for use on a mooring to maximize data return, and data processing techniques including phase-ambiguity unwrapping, spectral analysis, and a correction for instrument response. The method was used in the Salinity Processes Upper-ocean Regional Study (SPURS) to collect two year-long data sets. We find the mooring-derived TKE dissipation rates compare favorably to estimates made nearby from a microstructure shear probe mounted to a glider during its two separate two-week missions for (10 −8 ) ≤ ϵ ≤ (10 −5 ) m 2 s −3 . Periods of disagreement between turbulence estimates from the two platforms coincide with differences in vertical temperature profiles, which may indicate that barrier layers can substantially modulate upper-ocean turbulence over horizontal scales of 1-10 km. We also find that dissipation estimates from two different moorings at 12.5 m, and at 7 m are in agreement with the surface buoyancy flux during periods of strong nighttime convection, consistent with classic boundary layer theory.more » « less
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Abstract: The ocean absorbs one quarter of the global CO2 emissions from human activity. The community-led Surface Ocean CO2 Atlas (www.socat.info) is key for the quantification of ocean CO2 uptake and its variation, now and in the future. SOCAT version 2025 has quality-controlled in situ surface ocean fCO2 (fugacity of CO2) measurements on ships, moorings, sailing yachts, autonomous and drifting surface platforms for the global ocean and coastal seas from 1957 to 2025. The main SOCAT synthesis and gridded products contain fCO2 values with an estimated accuracy of better than 5 μatm. Sensor fCO2 data with an estimated accuracy of better than 10 μatm are separately available. During secondary quality control, marine scientists assign a flag to each data set, as well as WOCE flags of 2 (good), 3 (questionable) or 4 (bad) to individual fCO2 values. Data sets are assigned flags of A and B for an estimated accuracy of better than 2 μatm, flag of C (and D) for an accuracy of better than 5 μatm and a flag of E for an accuracy of better than 10 μatm. Bakker et al. (2016) describe the quality control criteria used from SOCAT version 3 onward. SOCAT quality control cookbooks provide quality control updates (www.socat.info), with (Gkritzalis et al., 2024) used for version 2025. Quality control comments for individual data sets can be accessed via the SOCAT Data Set Viewer (www.socat.info). All data sets, where data quality has been deemed acceptable, have been made public. The main SOCAT synthesis files and the gridded products contain all data sets with an estimated accuracy of better than 5 µatm (data set flags of A to D) and fCO2 values with a WOCE flag of 2. Access to data sets with an estimated accuracy of better than 10 µatm (flag of E) and fCO2 values with flags of 3 and 4 is via additional data products and the Data Set Viewer (Table 8 in Bakker et al., 2016). SOCAT publishes a global gridded product with a 1° longitude by 1° latitude resolution without gap filling. A second product with a higher resolution of 0.25° longitude by 0.25° latitude is available for the coastal seas. The gridded products contain all data sets with an estimated accuracy of better than 5 µatm (data set flags of A to D) and fCO2 values with a WOCE flag of 2. Gridded products are available monthly, per year and per decade. Two powerful, interactive, online viewers, the Data Set Viewer and the Gridded Data Viewer (www.socat.info), enable investigation of the SOCAT synthesis and gridded data products. SOCAT data products can be downloaded. Matlab code is available for reading these files. Ocean Data View also provides access to the SOCAT data products (www.socat.info). SOCAT data products are discoverable, accessible and citable. The SOCAT Data Use Statement (www.socat.info) asks users to generously acknowledge the contribution of SOCAT scientists by invitation to co-authorship, especially for data providers in regional studies, and/or reference to relevant scientific articles. It also asks users to cite the relevant SOCAT data set, the relevant methods paper(s), and to use acknowledgement text (https://socat.info/index.php/citing-socat/). The SOCAT website (www.socat.info) provides a single access point for online viewers, downloadable data sets, the Data Use Statement, a list of contributors and an overview of scientific publications on SOCAT and using SOCAT. Automation of data upload and initial data checks have allowed annual releases of SOCAT from version 4 onwards. Automation of metadata upload is ongoing. SOCAT is used for quantification of ocean CO2 uptake and ocean acidification and for evaluation of earth system models and sensor data. SOCAT products inform on ocean CO2 uptake in the annual Global Carbon Budget since 2013. SOCAT is a key element of the World Meteorological Organization’s (WMO) Global Greenhouse Gas Watch (G3W) program and is a key resource for Copernicus’ evaluations. The annual SOCAT releases by the SOCAT scientific community contribute to United Nations (UN) Sustainable Development Goal (SDG) 13 and SDG 14 (Life Below Water), and to the UN Decade of Ocean Science for Sustainable Development. However, since 2022 SOCAT critically relies on support provided by the Pacific Marine Environmental Laboratory of the National Oceanic and Atmospheric Administration in the US. This has been sufficient to keep the basic operation running, however this limited support has resulted in SOCAT data architecture not being updated, leading to a system with limited resilience that is highly vulnerable to external factors. Hundreds of peer-reviewed scientific publications and high-impact reports cite SOCAT. The SOCAT community-led synthesis product is a key step in the value chain based on in situ surface ocean carbon measurements, which provides policy makers with critical information on ocean CO2 uptake for policy makers. The need for accurate knowledge of global ocean CO2 uptake and its (future) variation makes sustained funding of in situ surface ocean CO2 observations and their synthesis imperative.more » « less
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