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Creators/Authors contains: "Whittington, Alan"

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  1. Abstract Melt composition, temperature, and crystallinity are often seen as the three most important characteristics driving lava rheology, which controls eruptive behavior. Traditional methods of measuring the viscosity of crystallizing basalts often yield different mineral characteristics to natural samples and are typically bubble-free. To quantify the viscosity of basalts inclusive of bubble and crystal cargo, we developed a new technique to measure high-temperature three-phase isothermal lava viscosity and applied it to samples from the 2018 eruption of Kīlauea. This new experimental technique begins at subliquidus temperatures, preserving original phenocrysts. A short experimental duration allows for the retention of most of the original bubble population (19%–31% vs. 36% in the original lava) and accurate replication of crystal textures from field samples, as documented in quenched postexperiment samples. The observed rheological behavior in these experiments, conducted at syneruptive temperatures (1150–1105 °C) and strain rates (0.4–18 s–1), should therefore be representative of the lava flows. We measured average viscosities of 116 Pa·s at 1150 °C to 167 Pa·s at 1115 °C (i.e., only 10%–25% higher than calculated liquid viscosities at those temperatures) and a maximum of 1800 Pa·s at 1105 °C. These results are much lower than viscosity measured in traditional bubble-free experiments, which plateaued at ~14,000 Pa·s at 1115 °C. Our results suggest the effect of bubbles in three-phase magmas may be greater than predicted by models based on two-phase bubbly liquids, and this effect must be included in realistic lava flow rheology models. The method proposed here supplies a framework for providing the necessary experimental constraints. 
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  2. Abstract We show that recalescence, or spontaneous reheating of a cooling material due to rapid release of latent heat, can occur during disequilibrium crystallization of depolymerized Mg-rich melts. This can only happen at fast cooling rates, where the melt becomes undercooled by tens to hundreds of degrees before crystallization begins. Using a forward-looking infrared (FLIR) camera, we documented recalescence in pyroxene (Fe, Mg)SiO3 and komatiite lavas that initially cooled at 25–50 °C s–1. Local heating at the crystallization front exceeds 150 °C for the pyroxene and 10 °C for komatiite and lasts for several seconds as the crystallization front migrates through. We determined the latent heat release by differential scanning calorimetry to be 440 J g–1 for pyroxene and 275 J g–1 for komatiite with a brief power output of ∼100 W g–1 or ∼300 MW m–3. Recalescence may be a widespread process in the solar system, particularly in lava fountains, and cooling histories of mafic pyroclasts should not be assumed a priori to be monotonic. 
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