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Betz, Markus; Elezzabi, Abdulhakem Y (Ed.)SnS2 is a two-dimensional (2D) layered semiconductor with a visible-range bandgap (~2.3eV), high charge carrier mobility, long carrier lifetimes, and good environmental stability. This study explores the impact of zero-valent metal intercalation into the van der Waals gaps of SnS2 on charge carrier dynamics. We demonstrate that metal intercalation enhances optical absorption in the yellow-to-IR range and induces metal-dependent bandgap shifts. Time-resolved THz spectroscopy reveals that different metals uniquely influence photoconductivity dynamics: We find that intercalation with Bi, Ni, and Fe shortens the photoconductivity decay times, whereas Rh intercalation results in a slower decay. These findings highlight the potential of metal intercalation to tailor SnS2 properties for diverse applications, from solar energy conversion to high-speed photodetectors.more » « lessFree, publicly-accessible full text available March 19, 2026
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Treichel, Megan; Xun, Ruiran; Williams, Camille F.; Gaitor, Jamie C.; MacMillan, Samantha N.; Vinskus, Jessica L.; Womble, C. Tyler; Kowalewski, Tomasz; Noonan, Kevin J. (, The Journal of Organic Chemistry)
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