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Wofford, Joshua D. ; Lindahl, Paul A. ( , BMC Systems Biology)
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Burns, Corey P. ; Yang, Xin ; Wofford, Joshua D. ; Bhuvanesh, Nattamai S. ; Hall, Michael B. ; Nippe, Michael ( , Angewandte Chemie International Edition)
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Burns, Corey P. ; Yang, Xin ; Sung, Siyoung ; Wofford, Joshua D. ; Bhuvanesh, Nattamai S. ; Hall, Michael B. ; Nippe, Michael ( , Chemical Communications)The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp 2 2− (PyCp 2 2− = [2,6-(CH 2 C 5 H 3 ) 2 C 5 H 3 N] 2− ) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce–Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy–Fe bonded species.more » « less