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none (Ed.)The recent prediction that honeycomb lattices of Co2+ (3d7) ions could host dominant Kitaev interactions provides an exciting direction for exploration of new routes to stabilizing Kitaev’s quantum spin liquid in real materials. Na3Co2SbO6 has been singled out as a potential material candidate provided that spin and orbital moments couple into a Jeff = 1/2 ground state, and that the relative strength of trigonal crystal field and spin-orbit coupling acting on Co ions can be tailored. Using x-ray linear dichroism (XLD) and x-ray magnetic circular dichroism (XMCD) experiments, alongside configuration interaction calculations, we confirm the counterintuitive positive sign of the trigonal crystal field acting on Co2+ ions and test the validity of the Jeff = 1/2 description of the electronic ground state. The results lend experimental support to recent theoretical predictions that a compression (elongation) of CoO6 octahedra along (perpendicular to) the trigonal axis would drive this cobaltate toward the Kitaev limit, assuming the Jeff = 1/2 character of the electronic ground state is preserved.more » « less
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Free, publicly-accessible full text available January 1, 2025
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null (Ed.)The current study investigates how and under what conditions family obligation benefits Mexican American adolescents’ adjustment. The study used two waves of data from 604 Mexican American adolescents (54.3% female, Mage.wave1 = 12.41 years, SD = 0.97) and their parents. Structural equation modeling revealed that both adolescents’ and parents’ sense of family obligation related to more supportive parenting (i.e., parental monitoring, warmth, and inductive reasoning), which linked to better adolescent adjustment (i.e., sense of life meaning, resilience, and grades). There were parent gender differences: Adolescents’ family obligation was more strongly related to their reports of maternal (vs. paternal) parenting. The links also varied across informants for parenting: (a) individuals’ sense of family obligation related only to their own perceptions of parenting and (b) there were more evident associations between adolescent-reported (vs. parent-reported) parenting and adolescent outcomes.more » « less