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Abstract Metal-free electrocatalysts represent a main branch of active materials for oxygen evolution reaction (OER), but they excessively rely on functionalized conjugated carbon materials, which substantially restricts the screening of potential efficient carbonaceous electrocatalysts. Herein, we demonstrate that a mesostructured polyacrylate hydrogel can afford an unexpected and exceptional OER activity – on par with that of benchmark IrO 2 catalyst in alkaline electrolyte, together with a high durability and good adaptability in various pH environments. Combined theoretical and electrokinetic studies reveal that the positively charged carbon atoms within the carboxylate units are intrinsically active toward OER, and spectroscopic operando characterizations also identify the fingerprint superoxide intermediate generated on the polymeric hydrogel backbone. This work expands the scope of metal-free materials for OER by providing a new class of polymeric hydrogel electrocatalysts with huge extension potentials. 

Abstract An effective approach was developed for identifying and correcting ocean-bottom seismometer (OBS) time errors through improving ambient noise cross-correlation function (NCCF) analysis and combination with other methods. Significant improvements were illustrated through analyzing data from a passive-source seismic experiment in the southwestern sub-basin of the South China Sea. A novel method was first developed that can effectively identify errors in the sampling frequency of the OBS instruments. The traditional NCCF method was then expanded by increasing the analyzed data spectrum from a single-frequency band to dual-frequency band pairs, thus doubling the number of available data points and substantially improving the time correction quality. For data with relatively low signal-to-noise ratios, the average time errors were reduced from the original average values of 60–80 ms by the conventional methods to <40  ms using the improved approaches. The new multistep procedure developed in this study has general applicability to analysis of other OBS experiments. The demonstrated significant improvements in the data quality are critical for advancing seismic tomography and other modern marine geophysical studies that require high accuracy in the OBS data.