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Abstract Colloidal Janus particles with well‐controlled parameters are sought for a range of applications in mesoscale self‐assembly, stabilization of Pickering emulsion, and development of multifunctional devices, among others. Herein, a versatile method for fabricating polystyrene‐silica (PS‐SiO₂) Janus particles featuring complex shapes and structures is developed by swelling PS@SiO₂core–shell spheroids. When the PS encapsulated in a rigid SiO₂shell is swollen by a good solvent for PS, the swelling‐induced pressure will result in an uneven distribution of stress acting on the SiO₂shell, as determined by the intrinsic symmetry of a spheroid. When the stress reaches a threshold value, the swollen PS will preferentially poke out from equatorial sites on the SiO₂shell to form T‐shaped Janus particles comprised of PS and SiO₂compartments. The size of the PS portion can be controlled by varying the extent of swelling, while the size, shape, and shell thickness of the SiO₂portion are determined by the original PS spheroids and the SiO₂coating. This solution‐phase method holds promise to produce Janus particles with diverse shapes, structures, and compositions for various applications. The T‐shaped Janus particles can serve as an emulsifier to effectively stabilize an oil‐in‐water (O/W) Pickering emulsion for at least 35 days.