Adiabatic decompression of paraquadrupolar materials has significant potential as a cryogenic cooling technology. We focus on TmVO
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, an archetypal material that undergoes a continuous phase transition to a ferroquadrupole-ordered state at 2.15 K. Above the phase transition, each Tm ion contributes an entropy of due to the degeneracy of the crystal electric field groundstate. Owing to the large magnetoelastic coupling, which is a prerequisite for a material to undergo a phase transition via the cooperative Jahn–Teller effect, this level splitting, and hence the entropy, can be readily tuned by externally induced strain. Using a dynamic technique in which the strain is rapidly oscillated, we measure the adiabatic elastocaloric response of single-crystal TmVO , and thus experimentally obtain the entropy landscape as a function of strain and temperature. The measurement confirms the suitability of this class of materials for cryogenic cooling applications and provides insight into the dynamic quadrupole strain susceptibility. Free, publicly-accessible full text available June 18, 2025 -
Butch, Nicholas P. ; Ran, Sheng ; Saha, Shanta R. ; Neves, Paul M. ; Zic, Mark P. ; Paglione, Johnpierre ; Gladchenko, Sergiy ; Ye, Qiang ; Rodriguez-Rivera, Jose A. ( , npj Quantum Materials)
Abstract The temperature dependence of the low-energy magnetic excitations in the spin-triplet superconductor UTe2was measured via inelastic neutron scattering in the normal and superconducting states. These excitations have a peak instensity at 4 meV, follow the Brillouin zone edges near the crystallographic b-axis, obey the paramagnetic structural symmetry, and track the temperature evolution of the heavy fermion bulk magnetic susceptibility. Thus, the imaginary part of the dynamic susceptibility follows the behavior of interband correlations in a hybridized Kondo lattice with an appropriate characteristic energy. These excitations are a lower-dimensional analog of phenomena observed in other Kondo lattice materials, such that their presence is not necessarily due to dominance of ferromagnetic or antiferromagnetic correlations. The onset of superconductivity alters the magnetic excitations noticeably on the same energy scales, suggesting that these changes originate from additional electronic structure modification.
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Zic, Mark P. ; Fuhrman, Wesley T. ; Wang, Kefeng ; Ran, Sheng ; Paglione, Johnpierre ; Butch, Nicholas P. ( , Journal of Applied Physics)