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Creators/Authors contains: "Zybura, Patrycia_K"

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  1. ; ; ; (, European Journal of Organic Chemistry)
    Abstract This manuscript describes a study of diverse reaction outcomes that stem from the ionization ofaza‐alkynyl‐Prins adducts. Experimental results have demonstrated unexpected behavior in the nitrogen‐containing systems compared to the analogous oxygen derivatives derived fromoxa‐Prins/halo‐Nazarov sequences. In‐depth experimental studies and computational analysis revealed an intricate mechanism involving competinghalo‐Nazarov andimino‐Nazarov pathways. These findings further elucidate the reaction chemistry of 3‐halo‐pentadienyl cation intermediates, and expand their utility in synthetic transformations. 
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