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  1. Free, publicly-accessible full text available December 1, 2024
  2. Free, publicly-accessible full text available May 4, 2024
  3. We present high resolution measurements of atmospheric methane (CH4) and nitrogen isotopic composition (d15N-N2) in the Greenland Ice Sheet Project Two (GISP2) Ice core. The data span Marine Isotope Stage 3, 13 to 50 thousand years (ka) before present. These datasets enhance our understanding of abrupt climate variability during the last glacial period, with a focus on Heinrich events 1 through 5. CH4 data were analyzed between 2014 and 2020 via an established wet extraction technique (Mitchell et al. 2013). Concentrations were determined via gas chromatography measurements on an Agilent 6890N and calibrated to the NOAA04 scale. d15N-N2 data were measured between 2017 and 2020 on a Finnigan MAT Delta XP via an established technique (Petrenko et al. 2006). The methane data allow for gas-phase synchronization of the GISP2 ice core to other polar ice cores from Greenland and Antarctica. The nitrogen isotopic composition data allow for reconstruction of abrupt Greenland surface climate variations. 
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  4. Abstract. Here we present a newly developed ice core gas-phase proxy that directlysamples a component of the large-scale atmospheric circulation:synoptic-scale pressure variability. Surface pressure changes weakly disrupt gravitational isotopic settling in the firn layer, which is recorded in krypton-86 excess (86Krxs). The 86Krxs may therefore reflect the time-averaged synoptic pressure variability over several years (site “storminess”), but it likely cannot record individual synoptic events as ice core gas samples typically average over several years. We validate 86Krxs using late Holocene ice samples from 11 Antarctic ice cores and 1 Greenland ice core that collectively represent a wide range of surface pressure variability in the modern climate. We find a strong spatial correlation (r=-0.94, p<0.01) between site average 86Krxs and time-averaged synoptic variability from reanalysis data. The main uncertainties in the analysis are the corrections for gas loss and thermal fractionation and the relatively large scatter in the data. Limited scientific understanding of the firn physics and potential biases of 86Krxs require caution in interpreting this proxy at present. We show that Antarctic 86Krxs appears to be linked to the position of the Southern Hemisphere eddy-driven subpolar jet (SPJ), with a southern position enhancing pressure variability. We present a 86Krxs record covering the last 24 kyr from the West Antarctic Ice Sheet (WAIS) Divide ice core. Based on the empirical spatial correlation of synoptic activity and 86Krxs at various Antarctic sites, we interpret this record to show that West Antarctic synoptic activity is slightly below modern levels during the Last Glacial Maximum (LGM), increases during the Heinrich Stadial 1 and Younger Dryas North Atlantic cold periods, weakens abruptly at the Holocene onset, remains low during the early and mid-Holocene, and gradually increases to its modern value. The WAIS Divide 86Krxs record resembles records of monsoon intensity thought to reflect changes in the meridional position of the Intertropical Convergence Zone (ITCZ) on orbital and millennial timescales such that West Antarctic storminess is weaker when the ITCZ is displaced northward and stronger when it is displaced southward. We interpret variations in synoptic activity as reflecting movement of the South Pacific SPJ in parallel to the ITCZ migrations, which is the expected zonal mean response of the eddy-driven jet in models and proxy data. Past changes to Pacific climate and the El Niño–Southern Oscillation (ENSO) may amplify the signal of the SPJ migration. Our interpretation is broadly consistent with opal flux records from the Pacific Antarctic zone thought to reflect wind-driven upwelling. We emphasize that 86Krxs is a new proxy, and more work is called for to confirm, replicate, and better understand these results; until such time, our conclusions regarding past atmospheric dynamics remainspeculative. Current scientific understanding of firn air transport andtrapping is insufficient to explain all the observed variations in86Krxs. A list of suggested future studies is provided. 
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  5. null (Ed.)
    Abstract The stable isotope ratios of oxygen and hydrogen in polar ice cores are known to record environmental change, and they have been widely used as a paleothermometer. Although it is known to be a simplification, the relationship is often explained by invoking a single condensation pathway with progressive distillation to the temperature at the location of the ice core. In reality, the physical factors are complicated, and recent studies have identified robust aspects of the hydrologic cycle’s response to climate change that could influence the isotope-temperature relationship. In this study, we introduce a new zonal-mean isotope model derived from radiative transfer theory, and incorporate it into a recently developed moist energy balance climate model (MEBM), thus providing an internally consistent representation of the tight physical coupling between temperature, hydrology, and isotope ratios in the zonal-mean climate. The isotope model reproduces the observed pattern of meteoric δ 18 O in the modern climate, and allows us to evaluate the relative importance of different processes for the temporal correlation between δ 18 O and temperature at high latitudes. We find that the positive temporal correlation in polar ice cores is predominantly a result of suppressed high-latitude evaporation with cooling, rather than local temperature changes. The same mechanism also explains the difference in the strength of the isotope-temperature relationship between Greenland and Antarctica. 
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  6. Abrupt climate changes during the last deglaciation have been well preserved in proxy records across the globe. However, one long-standing puzzle is the apparent absence of the onset of the Heinrich Stadial 1 (HS1) cold event around 18 ka in Greenland ice core oxygen isotope δ 18 O records, inconsistent with other proxies. Here, combining proxy records with an isotope-enabled transient deglacial simulation, we propose that a substantial HS1 cooling onset did indeed occur over the Arctic in winter. However, this cooling signal in the depleted oxygen isotopic composition is completely compensated by the enrichment because of the loss of winter precipitation in response to sea ice expansion associated with AMOC slowdown during extreme glacial climate. In contrast, the Arctic summer warmed during HS1 and YD because of increased insolation and greenhouse gases, consistent with snowline reconstructions. Our work suggests that Greenland δ 18 O may substantially underestimate temperature variability during cold glacial conditions. 
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  7. This data set is part of a joint international effort for the East GReenland Ice-core Project (EGRIP), which has retrieved an ice core by drilling through the Northeast Greenland Ice Stream (NEGIS, 75.63°N (North), 35.98°W (West)). Ice streams are responsible for draining a significant fraction of the ice from the Greenland Ice Sheet (GIS), and the project was developed to gain new and fundamental information on ice stream dynamics, thereby improving the understanding of how ice streams will contribute to future sea-level change. The drilled core also provides a new record of past climatic conditions from the northeastern part of the GIS. The project has many international partners and is managed by the Centre for Ice and Climate, Denmark with air support carried out by US ski-equipped Hercules aircraft managed through the US (United States) Office of Polar Programs, National Science Foundation. As of May 2022, approximately 2099.2 m (meters) of ice core have been recovered from the combined efforts of drilling operations in 2017, 2018, and 2019. Here we present records of stable isotopes of oxygen and hydrogen from 21.5 meters to 2120.7 m depth. Bedrock is estimated to be at a depth of approximately 2550 m; the remaining ice is expected to be recovered in the 2022 and 2023 field seasons. The data product presented here is supported by the National Science Foundation project: Collaborative Research: The fingerprint of abrupt temperature events throughout Greenland during the last glacial period. Award # 1804098. 
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  8. This data set is part of a joint international effort for the East GReenland Ice-core Project (EGRIP), which has retrieved an ice core by drilling through the Northeast Greenland Ice Stream (NEGIS, 75.63°N (North), 35.98°W (West)). Ice streams are responsible for draining a significant fraction of the ice from the Greenland Ice Sheet (GIS), and the project was developed to gain new and fundamental information on ice stream dynamics, thereby improving the understanding of how ice streams will contribute to future sea-level change. The drilled core also provides a new record of past climatic conditions from the northeastern part of the GIS. The project has many international partners and is managed by the Centre for Ice and Climate, Denmark with air support carried out by US ski-equipped Hercules aircraft managed through the US (United States) Office of Polar Programs, National Science Foundation. As of May 2022, approximately 2099.2 m (meters) of ice core have been recovered from the combined efforts of drilling operations in 2017, 2018, and 2019. Here we present records of stable isotopes of oxygen and hydrogen from 21.5 meters to 2120.7 m depth. Bedrock is estimated to be at a depth of approximately 2550 m; the remaining ice is expected to be recovered in the 2022 and 2023 field seasons. The data product presented here is supported by the National Science Foundation project: Collaborative Research: The fingerprint of abrupt temperature events throughout Greenland during the last glacial period. Award # 1804098. 
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