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Molecular hydrogen allows cooling in primordial gas, facilitating its collapse into Population III stars within primordial halos. Lyman–Werner (LW) radiation from these stars can escape the halo and delay further star formation by destroying H2 in other halos. As cosmological simulations show that increasing the background LW field strength increases the average halo mass required for star formation, we perform follow-up simulations of selected halos to investigate the knock-on effects this has on the Population III IMF. We follow 5 halos for each of the J21  = 0, 0.01, and 0.1 LW field strengths, resolving the pre-stellar core density of 10−6 g cm−3 (1018 cm−3) before inserting sink particles and following the fragmentation behaviour for hundreds of years further. We find that the mass accreted onto sinks by the end of the simulations is proportional to the mass within the ∼10−2 pc molecular core, which is not correlated to the initial mass of the halo. As such, the IMFs for masses above the brown dwarf limit show little dependence on the LW strength, although they do show variance in the number of low-mass clumps formed. As the range of background LW field strengths tested here covers the most likely values from literature, we conclude that the IMF for so-called Pop III.2 stars is not significantly different from the initial population of Pop III.1 stars. The primordial IMF therefore likely remains unchanged until the formation of the next generation of Population II stars.

 

ABSTRACT To investigate how molecular clouds react to different environmental conditions at a galactic scale, we present a catalogue of giant molecular clouds (GMCs) resolved down to masses of ∼10 M⊙ from a simulation of the entire disc of an interacting M51-like galaxy and a comparable isolated galaxy. Our model includes time-dependent gas chemistry, sink particles for star formation, and supernova feedback, meaning we are not reliant on star formation recipes based on threshold densities and can follow the physics of the cold molecular phase. We extract GMCs from the simulations and analyse their properties. In the disc of our simulated galaxies, spiral arms seem to act merely as snowplows, gathering gas, and clouds without dramatically affecting their properties. In the centre of the galaxy, on the other hand, environmental conditions lead to larger, more massive clouds. While the galaxy interaction has little effect on cloud masses and sizes, it does promote the formation of counter-rotating clouds. We find that the identified clouds seem to be largely gravitationally unbound at first glance, but a closer analysis of the hierarchical structure of the molecular interstellar medium shows that there is a large range of virial parameters with a smooth transition from unbound to mostly bound for the densest structures. The common observation that clouds appear to be virialized entities may therefore be due to CO bright emission highlighting a specific level in this hierarchical binding sequence. The small fraction of gravitationally bound structures found suggests that low galactic star formation efficiencies may be set by the process of cloud formation and initial collapse. 

ABSTRACT We use hydrodynamical simulations to study the Milky Way’s central molecular zone (CMZ). The simulations include a non-equilibrium chemical network, the gas self-gravity, star formation, and supernova feedback. We resolve the structure of the interstellar medium at sub-parsec resolution while also capturing the interaction between the CMZ and the bar-driven large-scale flow out to $R\sim 5\, {\rm kpc}$. Our main findings are as follows: (1) The distinction between inner (R ≲ 120 pc) and outer (120 ≲ R ≲ 450 pc) CMZ that is sometimes proposed in the literature is unnecessary. Instead, the CMZ is best described as single structure, namely a star-forming ring with outer radius R ≃ 200 pc which includes the 1.3° complex and which is directly interacting with the dust lanes that mediate the bar-driven inflow. (2) This accretion can induce a significant tilt of the CMZ out of the plane. A tilted CMZ might provide an alternative explanation to the ∞-shaped structure identified in Herschel data by Molinari et al. (3) The bar in our simulation efficiently drives an inflow from the Galactic disc (R ≃ 3 kpc) down to the CMZ (R ≃ 200 pc) of the order of $1\rm \, M_\odot \, yr^{-1}$, consistent with observational determinations. (4) Supernova feedback can drive an inflow from the CMZ inwards towards the circumnuclear disc of the order of ${\sim}0.03\, \rm M_\odot \, yr^{-1}$. (5) We give a new interpretation for the 3D placement of the 20 and 50 km s−1 clouds, according to which they are close (R ≲ 30 pc) to the Galactic Centre, but are also connected to the larger scale streams at R ≳ 100 pc. 

Abstract The Milky Way’s central molecular zone (CMZ) has emerged in recent years as a unique laboratory for the study of star formation. Here we use the simulations presented in Tress et al. 2020 to investigate star formation in the CMZ. These simulations resolve the structure of the interstellar medium at sub-parsec resolution while also including the large-scale flow in which the CMZ is embedded. Our main findings are as follows. (1) While most of the star formation happens in the CMZ ring at R ≳ 100 pc, a significant amount also occurs closer to SgrA* at R ≲ 10 pc. (2) Most of the star formation in the CMZ happens downstream of the apocentres, consistent with the “pearls-on-a-string” scenario, and in contrast to the notion that an absolute evolutionary timeline of star formation is triggered by pericentre passage. (3) Within the timescale of our simulations (∼100 Myr), the depletion time of the CMZ is constant within a factor of ∼2. This suggests that variations in the star formation rate are primarily driven by variations in the mass of the CMZ, caused for example by AGN feedback or externally-induced changes in the bar-driven inflow rate, and not by variations in the depletion time. (4) We study the trajectories of newly born stars in our simulations. We find several examples that have age and 3D velocity compatible with those of the Arches and Quintuplet clusters. Our simulations suggest that these prominent clusters originated near the collision sites where the bar-driven inflow accretes onto the CMZ, at symmetrical locations with respect to the Galactic centre, and that they have already decoupled from the gas in which they were born. 

ABSTRACT Observations of molecular gas near the Galactic Centre (|l| < 10°, |b| < 1°) reveal the presence of a distinct population of enigmatic compact clouds that are characterized by extreme velocity dispersions ($\Delta v \gt 100\, {\rm km\, s^{-1}}$). These extended velocity features are very prominent in the data cubes and dominate the kinematics of molecular gas just outside the Central Molecular Zone (CMZ). The prototypical example of such a cloud is Bania Clump 2. We show that similar features are naturally produced in simulations of gas flow in a realistic barred potential. We analyse the structure of the features obtained in the simulations and use this to interpret the observations. We find that the features arise from collisions between material that has been infalling rapidly along the dust lanes of the Milky Way bar and material that belongs to one of the following two categories: (i) material that has ‘overshot’ after falling down the dust lanes on the opposite side; (ii) material which is part of the CMZ. Both types of collisions involve gas with large differences in the line-of-sight velocities, which is what produces the observed extreme velocity dispersions. Examples of both categories can be identified in the observations. If our interpretation is correct, we are directly witnessing (a) collisions of clouds with relative speeds of $\sim 200\, {\rm km\, s^{-1}}$ and (b) the process of accretion of fresh gas onto the CMZ. 

We present here the first of a series of papers aimed at better understanding the evolution and properties of giant molecular clouds (GMCs) in a galactic context. We perform high-resolution, three-dimensional arepo simulations of an interacting galaxy inspired by the well-observed M51 galaxy. Our fiducial simulations include a non-equilibrium, time-dependent, chemical network that follows the evolution of atomic and molecular hydrogen as well as carbon and oxygen self-consistently. Our calculations also treat gas self-gravity and subsequent star formation (described by sink particles), and coupled supernova feedback. In the densest parts of the simulated interstellar medium (ISM), we reach sub-parsec resolution, granting us the ability to resolve individual GMCs and their formation and destruction self-consistently throughout the galaxy. In this initial work, we focus on the general properties of the ISM with a particular focus on the cold star-forming gas. We discuss the role of the interaction with the companion galaxy in generating cold molecular gas and controlling stellar birth. We find that while the interaction drives large-scale gas flows and induces spiral arms in the galaxy, it is of secondary importance in determining gas fractions in the different ISM phases and the overall star formation rate. The behaviour of the gas on small GMC scales instead is mostly controlled by the self-regulating property of the ISM driven by coupled feedback.

 

We introduce a new suite of simulations, ‘The Cloud Factory’, which self-consistently forms molecular cloud complexes at high enough resolution to resolve internal substructure (up to 0.25 M⊙ in mass) all while including galactic-scale forces. We use a version of the arepo code modified to include a detailed treatment of the physics of the cold molecular ISM, and an analytical galactic gravitational potential for computational efficiency. The simulations have nested levels of resolution, with the lowest layer tied to tracer particles injected into individual cloud complexes. These tracer refinement regions are embedded in the larger simulation so continue to experience forces from outside the cloud. This allows the simulations to act as a laboratory for testing the effect of galactic environment on star formation. Here we introduce our method and investigate the effect of galactic environment on filamentary clouds. We find that cloud complexes formed after a clustered burst of feedback have shorter lengths and are less likely to fragment compared to quiescent clouds (e.g. the Musca filament) or those dominated by the galactic potential (e.g. Nessie). Spiral arms and differential rotation preferentially align filaments, but strong feedback randomizes them. Long filaments formed within the cloud complexes are necessarily coherent with low internal velocity gradients, which has implications for the formation of filamentary star-clusters. Cloud complexes formed in regions dominated by supernova feedback have fewer star-forming cores, and these are more widely distributed. These differences show galactic-scale forces can have a significant impact on star formation within molecular clouds.

 

A new di‐tert‐butyl acrylate (diTBA) monomer for controlled radical polymerization is reported. This monomer complements the classical use oftert‐butyl acrylate (TBA) for synthesis of poly(acrylic acid) by increasing the density of carboxylic acids per repeat unit, while also increasing the flexibility of the carboxylic acid side‐chains. The monomer is well behaved under Cu(II)‐mediated photoinduced controlled radical polymerization and delivers polymers with excellent chain‐end fidelity at high monomer conversions. Importantly, this new diTBA monomer readily copolymerizes with TBA to further the potential for applications in areas such as dispersing agents and adsorbents. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem.2017,55, 801–807

 

The synthesis and systematic comparison of a comprehensive library of well‐defined polymer architectures based on poly(acrylic acid) is reported. Through the development of new synthetic methodologies, linear, single branched, precision‐branched comb, and star polymers were prepared and their performance as dispersants was evaluated. The ability to accurately control chain lengths and branch points allows the subtle interplay between structure and dispersant performance to be defined and affords critical insights into the design of improved polymeric additives for coating formulations. The general industrial relevance of ionic polymers and branched macromolecular architectures supports these design rules for a wide range of other applications and materials, including as additives for personal care products and in water treatment. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem.2019,57, 716–725