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We present the first isotopic abundances of both¹³CO and C¹⁸O in solar twin stars and test the results against several galactic chemical evolution (GCE) models with different nucleosynthesis prescriptions. First, we compareM-band spectra from IRTF/iSHELL to synthetic spectra generated from custom solar atmosphere models using the PHOENIX atmosphere code. Next, we compare our calculated abundances to GCE models that consider isotopic yields from massive stars, asymptotic giant branch stars, and fast-rotating stars. The¹²C/¹³C ratios determined for this sample of solar twins are consistent with predictions from the selected GCE models; however, the¹⁶O/¹⁸O ratios tentatively contradict these predictions. This project constitutes the first in a stellar chemical abundance series seeking to (1) support the James Webb Space Telescope as it characterizes exoplanet atmospheres, interiors, and biosignatures by providing host star abundances; (2) identify how unexplored stellar abundances reveal the process of galactic chemical evolution and correlate with star formation, interior, age, metallicity, and activity; and (3) provide improved stellar ages using stellar abundance measurements. By measuring elemental and isotopic abundances in a variety of stars, we not only supply refined host star parameters, but also provide the necessary foundations for complementary exoplanet characterization studies—and ultimately contribute to the exploration of galactic, stellar, and planetary origins and evolution.

We present and confirm TOI-1751 b, a transiting sub-Neptune orbiting a slightly evolved, solar-type, metal-poor star (T_eff= 5996 ± 110 K,$\log (g)=4.2\pm 0.1$,V= 9.3 mag, [Fe/H] = −0.40 ± 0.06 dex) every 37.47 days. We use TESS photometry to measure a planet radius of${2.77}_{-0.07}^{+0.15}{R}_{\oplus }$. We also use both Keck/HIRES and APF/Levy radial velocities (RV) to derive a planet mass of${14.5}_{-3.14}^{+3.15}{M}_{\oplus }$, and thus a planet density of 3.6 ± 0.9 g cm⁻³. There is also a long-period (∼400 days) signal that is observed in only the Keck/HIRES data. We conclude that this long-period signal is not planetary in nature and is likely due to the window function of the Keck/HIRES observations. This highlights the role of complementary observations from multiple observatories to identify and exclude aliases in RV data. Finally, we investigate the potential compositions of this planet, including rocky and water-rich solutions, as well as theoretical irradiated ocean models. TOI-1751 b is a warm sub-Neptune with an equilibrium temperature of ∼820 K. As TOI-1751 is a metal-poor star, TOI-1751 b may have formed in a water-enriched formation environment. We thus favor a volatile-rich interior composition for this planet.

The extreme environments of ultra-short-period planets (USPs) make excellent laboratories to study how exoplanets obtain, lose, retain, and/or regain gaseous atmospheres. We present the confirmation and characterization of the USP TOI-1347 b, a 1.8 ± 0.1R_⊕planet on a 0.85 day orbit that was detected with photometry from the TESS mission. We measured radial velocities of the TOI-1347 system using Keck/HIRES and HARPS-N and found the USP to be unusually massive at 11.1 ± 1.2M_⊕. The measured mass and radius of TOI-1347 b imply an Earth-like bulk composition. A thin H/He envelope (>0.01% by mass) can be ruled out at high confidence. The system is between 1 and 1.8 Gyr old; therefore, intensive photoevaporation should have concluded. We detected a tentative phase-curve variation (3σ) and a secondary eclipse (2σ) in TESS photometry, which, if confirmed, could indicate the presence of a high-mean-molecular-weight atmosphere. We recommend additional optical and infrared observations to confirm the presence of an atmosphere and investigate its composition.

With JWST’s successful deployment and unexpectedly high fuel reserves, measuring the masses of sub-Neptunes transiting bright, nearby stars will soon become the bottleneck for characterizing the atmospheres of small exoplanets via transmission spectroscopy. Using a carefully curated target list and observations from more than 2 yr of APF-Levy and Keck-HIRES Doppler monitoring, the TESS-Keck Survey is working toward alleviating this pressure. Here we present mass measurements for 11 transiting planets in eight systems that are particularly suited to atmospheric follow-up with JWST. We also report the discovery and confirmation of a temperate super-Jovian-mass planet on a moderately eccentric orbit. The sample of eight host stars, which includes one subgiant, spans early-K to late-F spectral types (T_eff= 5200–6200 K). We homogeneously derive planet parameters using a joint photometry and radial velocity modeling framework, discuss the planets’ possible bulk compositions, and comment on their prospects for atmospheric characterization.

We report on the discovery and characterization of three planets orbiting the F8 star HD 28109, which sits comfortably in ${TESS}$’s continuous viewing zone. The two outer planets have periods of $\rm 56.0067 \pm 0.0003~d$ and $\rm 84.2597_{-0.0008}^{+0.0010}~d$, which implies a period ratio very close to that of the first-order 3:2 mean motion resonance, exciting transit timing variations (TTVs) of up to $\rm 60\, min$. These two planets were first identified by ${TESS}$, and we identified a third planet in the ${TESS}$photometry with a period of $\rm 22.8911 \pm 0.0004~d$. We confirm the planetary nature of all three planetary candidates using ground-based photometry from Hazelwood, ${ASTEP}$, and LCO, including a full detection of the $\rm \sim 9\, h$ transit of HD 28109 c from Antarctica. The radii of the three planets are ${\it R}_b=2.199_{-0.10}^{+0.098} ~{\rm R}_{\oplus }$, ${\it R}_c=4.23\pm 0.11~ {\rm R}_{\oplus }$, and ${\it R}_d=3.25\pm 0.11 ~{\rm R}_{\oplus }$; we characterize their masses using TTVs and precise radial velocities from ESPRESSO and HARPS, and find them to be ${\it M}_b=18.5_{-7.6}^{+9.1}~M_{\oplus }$, ${\it M}_c=7.9_{-3.0}^{+4.2}~{\rm M}_{\oplus }$, and ${\it M}_d=5.7_{-2.1}^{+2.7}~{\rm M}_{\oplus }$, making planet b a dense, massive planet while c and d are both underdense. We also demonstrate that the two outer planets are ripe for atmospheric characterization using transmission spectroscopy, especially given their position in the CVZ of James Webb Space Telescope. The data obtained to date are consistent with resonant (librating) and non-resonant (circulating) solutions; additional observations will show whether the pair is actually locked in resonance or just near-resonant.

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.