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Correlative Nanoscale Imaging of Strained hBN Spin Defects

https://doi.org/10.1021/acsami.2c11886

Curie, David ; Krogel, Jaron T. ; Cavar, Lukas ; Solanki, Abhishek ; Upadhyaya, Pramey ; Li, Tongcang ; Pai, Yun-Yi ; Chilcote, Michael ; Iyer, Vasudevan ; Puretzky, Alexander ; et al ( September 2022 , ACS Applied Materials & Interfaces)

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K 2 CuX 3 (X = Cl, Br): All-Inorganic Lead-Free Blue Emitters with Near-Unity Photoluminescence Quantum Yield

https://doi.org/10.1021/acs.chemmater.0c02098

Creason, Tielyr D. ; McWhorter, Timothy M. ; Bell, Zane ; Du, Mao-Hua ; Saparov, Bayrammurad ( July 2020 , Chemistry of Materials)

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Reaching 90% Photoluminescence Quantum Yield in One-Dimensional Metal Halide C 4 N 2 H 14 PbBr 4 by Pressure-Suppressed Nonradiative Loss

https://doi.org/10.1021/jacs.0c07166

Wang, Yingqi ; Guo, Songhao ; Luo, Hui ; Zhou, Chenkun ; Lin, Haoran ; Ma, Xuedan ; Hu, Qingyang ; Du, Mao-hua ; Ma, Biwu ; Yang, Wenge ; et al ( September 2020 , Journal of the American Chemical Society)

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Highly Efficient Broad-Band Luminescence Involving Organic and Inorganic Molecules in a Zero-Dimensional Hybrid Lead Chloride

https://doi.org/10.1021/acs.jpcc.9b05509

Yangui, Aymen ; Roccanova, Rachel ; Wu, Yuntao ; Du, Mao-Hua ; Saparov, Bayrammurad ( August 2019 , The Journal of Physical Chemistry C)

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0D and 2D: The Cases of Phenylethylammonium Tin Bromide Hybrids

https://doi.org/10.1021/acs.chemmater.0c01254

Xu, Liang-Jin ; Lin, Haoran ; Lee, Sujin ; Zhou, Chenkun ; Worku, Michael ; Chaaban, Maya ; He, Qingquan ; Plaviak, Anna ; Lin, Xinsong ; Chen, Banghao ; et al ( June 2020 , Chemistry of Materials)

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Hybrid Organic–Inorganic Halides (C 5 H 7 N 2 ) 2 MBr 4 (M = Hg, Zn) with High Color Rendering Index and High-Efficiency White-Light Emission

https://doi.org/10.1021/acs.chemmater.9b00537

Yangui, Aymen ; Roccanova, Rachel ; McWhorter, Timothy M. ; Wu, Yuntao ; Du, Mao-Hua ; Saparov, Bayrammurad ( March 2019 , Chemistry of Materials)

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(C 7 H 11 N 2 ) 2 MBr 4 (M=Cu, Zn): X‐Ray Sensitive 0D Hybrid Metal Halides with Tunable Broadband Emission

https://doi.org/10.1002/ejic.202100954

McWhorter, Timothy M. ; Zhang, Zheng ; Creason, Tielyr D. ; Thomas, Leonard ; Du, Mao‐Hua ; Saparov, Bayram ( January 2022 , European Journal of Inorganic Chemistry)

Abstract
Herein, a new family of hybrid metal halides, (DMAP)₂MBr₄(M = Cu, Zn), featuring zero‐dimensional (0D), pseudo‐layered crystal structures containing isolated molecular 4‐dimethylaminopyridinium (DMAP, C₇H₁₁N₂⁺) cations and MBr₄²⁻tetrahedral anions are reported. (DMAP)₂MBr₄show remarkable long‐term stability, with no signs of degradation after one year of ambient air exposure. The reported solution synthesis affords large crystals measuring up to 1 cm, which showed significant response to soft 8 keV X‐ray photons when implemented into X‐ray detectors. Furthermore, (DMAP)₂ZnBr₄demonstrates tunable color light emission properties, which is attributed to the organic molecular units based on our combined experimental and computational results. The measured photoluminescence quantum yield (PLQY) for (DMAP)₂ZnBr₄is 7.35 %, a remarkable enhancement of emission efficiency as compared to a weak emission from the organic precursor. The inexpensive and earth‐abundant chemical compositions and ease of preparation of the new hybrid metal halides make them promising candidates for optical and electronic applications.

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Low dimensional metal halide perovskites and hybrids

https://doi.org/10.1016/j.mser.2018.12.001

Zhou, Chenkun ; Lin, Haoran ; He, Qingquan ; Xu, Liangjin ; Worku, Michael ; Chaaban, Maya ; Lee, Sujin ; Shi, Xiaoqin ; Du, Mao-Hua ; Ma, Biwu ( July 2019 , Materials Science and Engineering: R: Reports)

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Bulk Assembly of Zero-Dimensional Organic Lead Bromide Hybrid with Efficient Blue Emission

https://doi.org/10.1021/acsmaterialslett.9b00333

Lin, Haoran ; Zhou, Chenkun ; Chaaban, Maya ; Xu, Liang-Jin ; Zhou, Yan ; Neu, Jennifer ; Worku, Michael ; Berkwits, Ella ; He, Qingquan ; Lee, Sujin ; et al ( December 2019 , ACS Materials Letters)

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Rb 4 Ag 2 BiBr 9 : A Lead-Free Visible Light Absorbing Halide Semiconductor with Improved Stability

https://doi.org/10.1021/acs.inorgchem.8b03623

Sharma, Manila ; Yangui, Aymen ; Whiteside, Vincent R. ; Sellers, Ian R. ; Han, Dan ; Chen, Shiyou ; Du, Mao-Hua ; Saparov, Bayrammurad ( March 2019 , Inorganic Chemistry)

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