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Abstract A 15-yr duration record of mooring observations from the eastern (>70°E) Eurasian Basin (EB) of the Arctic Ocean is used to show and quantify the recently increased oceanic heat flux from intermediate-depth (~150–900 m) warm Atlantic Water (AW) to the surface mixed layer and sea ice. The upward release of AW heat is regulated by the stability of the overlying halocline, which we show has weakened substantially in recent years. Shoaling of the AW has also contributed, with observations in winter 2017–18 showing AW at only 80 m depth, just below the wintertime surface mixed layer, the shallowest in our mooring records. The weakening of the halocline for several months at this time implies that AW heat was linked to winter convection associated with brine rejection during sea ice formation. This resulted in a substantial increase of upward oceanic heat flux during the winter season, from an average of 3–4 W m −2 in 2007–08 to >10 W m −2 in 2016–18. This seasonal AW heat loss in the eastern EB is equivalent to a more than a twofold reduction of winter ice growth. These changes imply a positive feedback as reduced sea ice cover permits increased mixing, augmenting the summer-dominated ice-albedo feedback. 

Abstract The diffusive layering (DL) form of double-diffusive convection cools the Atlantic Water (AW) as it circulates around the Arctic Ocean. Large DL steps, with heights of homogeneous layers often greater than 10 m, have been found above the AW core in the Eurasian Basin (EB) of the eastern Arctic. Within these DL staircases, heat and salt fluxes are determined by the mechanisms for vertical transport through the high-gradient regions (HGRs) between the homogeneous layers. These HGRs can be thick (up to 5 m and more) and are frequently complex, being composed of multiple small steps or continuous stratification. Microstructure data collected in the EB in 2007 and 2008 are used to estimate heat fluxes through large steps in three ways: using the measured dissipation rate in the large homogeneous layers; utilizing empirical flux laws based on the density ratio and temperature step across HGRs after scaling to account for the presence of multiple small DL interfaces within each HGR; and averaging estimates of heat fluxes computed separately for individual small interfaces (as laminar conductive fluxes), small convective layers (via dissipation rates within small DL layers), and turbulent patches (using dissipation rate and buoyancy) within each HGR. Diapycnal heat fluxes through HGRs evaluated by each method agree with each other and range from ~2 to ~8 W m−2, with an average flux of ~3–4 W m−2. These large fluxes confirm a critical role for the DL instability in cooling and thickening the AW layer as it circulates around the eastern Arctic Ocean. 

In this work, the Coulson‐Longuet‐Higgins response function (atom‐atomic polarizabilities [AAPs]) is used to describe the transfer of an electron perturbation in π‐conjugated systems in the presence of a static electric field. Computations are performed using different many‐electron approaches to study the effect. An accurate account of the electron correlation is shown to play a key role in the description of the interaction of a π‐shell with the external electrostatic field. Studies in this work reveal that the Hückel theory widely used in calculations of electron‐perturbation transfer is not reliable even at the qualitative level to describe the effects studies in this work. However, the π‐electron coupled cluster theory has been proven capable of providing a reliable electronic structure (among them, AAPs and excitation energies) that agree with the results obtained with the π‐electron full configuration‐interaction approach. The calculations also show that these properties have an essentially nonlinear character in terms of the strength of the applied electric field. The results obtained in the present work can provide useful information relevant to the application of π‐conjugated systems in molecular electronics.

 

A 15‐year (2004–2018) record of mooring observations from the upper 50 m of the ocean in the eastern Eurasian Basin reveals increased current speeds and vertical shear, associated with an increasing coupling between wind, ice, and the upper ocean over 2004–2018, particularly in summer. Substantial increases in current speeds and shears in the upper 50 m are dominated by a two times amplification of currents in the semidiurnal band, which includes tides and wind‐forced near‐inertial oscillations. For the first time the strengthened upper ocean currents and shear are observed to coincide with weakening stratification. This coupling links the Atlantic Water heat to the sea ice, a consequence of which would be reducing regional sea ice volume. These results point to a new positive feedback mechanism in which reduced sea ice extent facilitates more energetic inertial oscillations and associated upper‐ocean shear, thus leading to enhanced ventilation of the Atlantic Water.