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  1. Abstract Cosmogenic radio-nuclei are an important source of background for low-energy neutrino experiments. In Borexino, cosmogenic $$^{11}$$ 11 C decays outnumber solar pep and CNO neutrino events by about ten to one. In order to extract the flux of these two neutrino species, a highly efficient identification of this background is mandatory. We present here the details of the most consolidated strategy, used throughout Borexino solar neutrino measurements. It hinges upon finding the space-time correlations between $$^{11}$$ 11 C decays, the preceding parent muons and the accompanying neutrons. This article describes the working principles and evaluates the performance of this Three-Fold Coincidence (TFC) technique in its two current implementations: a hard-cut and a likelihood-based approach. Both show stable performances throughout Borexino Phases II (2012–2016) and III (2016–2020) data sets, with a $$^{11}$$ 11 C tagging efficiency of $$\sim 90$$ ∼ 90  % and $$\sim $$ ∼  63–66 % of the exposure surviving the tagging. We present also a novel technique that targets specifically $$^{11}$$ 11 C produced in high-multiplicity during major spallation events. Such $$^{11}$$ 11 C appear as a burst of events, whose space-time correlation can be exploited. Burst identification can be combined with the TFC to obtain about the same tagging efficiency of $$\sim 90\%$$ ∼ 90 % but with a higher fraction of the exposure surviving, in the range of $$\sim $$ ∼  66–68 %. 
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    Abstract Neutrinos emitted in the carbon, nitrogen, oxygen (CNO) fusion cycle in the Sun are a sub-dominant, yet crucial component of solar neutrinos whose flux has not been measured yet. The Borexino experiment at the Laboratori Nazionali del Gran Sasso (Italy) has a unique opportunity to detect them directly thanks to the detector’s radiopurity and the precise understanding of the detector backgrounds. We discuss the sensitivity of Borexino to CNO neutrinos, which is based on the strategies we adopted to constrain the rates of the two most relevant background sources, $$pep$$ pep neutrinos from the solar pp -chain and $$^{210}$$ 210 Bi beta decays originating in the intrinsic contamination of the liquid scintillator with $$^{210}$$ 210 Pb. Assuming the CNO flux predicted by the high-metallicity Standard Solar Model and an exposure of 1000 days $$\times $$ × 71.3 t, Borexino has a median sensitivity to CNO neutrino higher than 3 $$\sigma $$ σ . With the same hypothesis the expected experimental uncertainty on the CNO neutrino flux is 23%, provided the uncertainty on the independent estimate of the $$^{210}\text {Bi}$$ 210 Bi  interaction rate is 1.5 $$\hbox {cpd}/100~\hbox {ton}$$ cpd / 100 ton  . Finally, we evaluated the expected uncertainty of the C and N abundances and the expected discrimination significance between the high and low metallicity Standard Solar Models (HZ and LZ) with future more precise measurement of the CNO solar neutrino flux. 
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