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Notwithstanding the large number of studies on bedforms such as dunes and antidunes, predicting equilibrium bedform type and geometry for a given flow regime, sediment supply and caliber remains an open problem. Here, we present results from laboratory experiments specifically designed to study how upper regime bedform type and geometry vary with sediment supply and caliber. Experiments were performed in a sediment feed flume with flow rates varying between 5 and 30 l/s and sand supply rates varying between 0.6 and 20 kg/min. We used both uniform and non‐uniform sands with geometric mean diameters varying between 0.22 and 0.87 mm. Analysis of our data and data available in the literature reveals that the ratio of total (bedload plus suspension) volume transport rate of sediment to water dischargeQ_s/Q_wplays a prime control on upper regime equilibrium beds. Equilibrium bedforms transition from washed out dunes (lower regime) to downstream migrating antidunes (upper regime) forQ_s/Q_wbetween 0.0003 and 0.0007. For values ofQ_s/Q_wgreater than 0.0015, the bedform length increases withQ_s/Q_w. At these high values ofQ_s/Q_w, equilibrium in fine sand is characterized by upstream migrating antidunes, cyclic steps, and significant suspended load. In experiments with coarse sand, equilibrium is characterized by plane bed with bedload transport in sheet flow mode. Standing waves form at the transition between downstream migrating antidunes and upstream migrating bedforms.

The cobalt complexes HCo(CO)₄and HCo(CO)₃(PR₃) were the original industrial catalysts used for the hydroformylation of alkenes through reaction with hydrogen and carbon monoxide to produce aldehydes. More recent and expensive rhodium-phosphine catalysts are hundreds of times more active and operate under considerably lower pressures. Cationic cobalt(II) bisphosphine hydrido-carbonyl catalysts that are far more active than traditional neutral cobalt(I) catalysts and approach rhodium catalysts in activity are reported here. These catalysts have low linear-to-branched (L:B) regioselectivity for simple linear alkenes. However, owing to their high alkene isomerization activity and increased steric effects due to the bisphosphine ligand, they have high L:B selectivities for internal alkenes with alkyl branches. These catalysts exhibit long lifetimes and substantial resistance to degradation reactions.