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We performed polarized reflection and transmission measurements on the layered conducting oxide PdCoO₂thin films. For theab-plane, an optical peak near Ω ≈ 750 cm⁻¹drives the scattering rate 1/τ(ω) and effective massm^*(ω) of the Drude carrier to increase and decrease respectively forω ≧ Ω. For thec-axis, a longitudinal optical phonon (LO) is present at Ω as evidenced by a peak in the loss function Im[−1/ε_c(ω)]. Further polarized measurements in different light propagation (q) and electric field (E) configurations indicate that the Peak at Ω results from an electron-phonon coupling of theab-plane carrier with thec-LO phonon, which leads to the frequency-dependent 1/τ(ω) andm^*(ω). This unusual interaction was previously reported in high-temperature superconductors (HTSC) between a non-Drude, mid-infrared (IR) band and ac-LO. On the contrary, it is the Drude carrier that couples in PdCoO₂. The coupling between theab-plane Drude carrier andc-LO suggests that thec-LO phonon may play a significant role in the characteristicab-plane electronic properties of PdCoO₂, including the ultra-high dc-conductivity, phonon-drag, and hydrodynamic electron transport.

 

An efficient application of a material is only possible if we know its physical and chemical properties, which is frequently obstructed by the presence of micro‐ or macroscopic inclusions of secondary phases. While sometimes a sophisticated synthesis route can address this issue, often obtaining pure material is not possible. One example is TaGeIr, which has highly sample‐dependent properties resulting from the presence of several impurity phases, which influence electronic transport in the material. The effect of these minority phases was avoided by manufacturing, with the help of focused‐ion‐beam, a μm‐scale device containing only one phase—TaGeIr. This work provides evidence for intrinsic semiconducting behavior of TaGeIr and serves as an example of selective single‐domain device manufacturing. This approach gives a unique access to the properties of compounds that cannot be synthesized in single‐phase form, sparing costly and time‐consuming synthesis efforts. 

The defining characteristic of hole-doped cuprates is d -wave high temperature superconductivity. However, intense theoretical interest is now focused on whether a pair density wave state (PDW) could coexist with cuprate superconductivity [D. F. Agterberg et al., Annu. Rev. Condens. Matter Phys. 11, 231 (2020)]. Here, we use a strong-coupling mean-field theory of cuprates, to model the atomic-scale electronic structure of an eight-unit-cell periodic, d -symmetry form factor, pair density wave (PDW) state coexisting with d -wave superconductivity (DSC). From this PDW + DSC model, the atomically resolved density of Bogoliubov quasiparticle states N r , E is predicted at the terminal BiO surface of Bi 2 Sr 2 CaCu 2 O 8 and compared with high-precision electronic visualization experiments using spectroscopic imaging scanning tunneling microscopy (STM). The PDW + DSC model predictions include the intraunit-cell structure and periodic modulations of N r , E , the modulations of the coherence peak energy Δ p r , and the characteristics of Bogoliubov quasiparticle interference in scattering-wavevector space q - space . Consistency between all these predictions and the corresponding experiments indicates that lightly hole-doped Bi 2 Sr 2 CaCu 2 O 8 does contain a PDW + DSC state. Moreover, in the model the PDW + DSC state becomes unstable to a pure DSC state at a critical hole density p *, with empirically equivalent phenomena occurring in the experiments. All these results are consistent with a picture in which the cuprate translational symmetry-breaking state is a PDW, the observed charge modulations are its consequence, the antinodal pseudogap is that of the PDW state, and the cuprate critical point at p * ≈ 19% occurs due to disappearance of this PDW. 

High magnetic fields suppress cuprate superconductivity to reveal an unusual density wave (DW) state coexisting with unexplained quantum oscillations. Although routinely labeled a charge density wave (CDW), this DW state could actually be an electron-pair density wave (PDW). To search for evidence of a field-induced PDW, we visualized modulations in the density of electronic states N ( r ) within the halo surrounding Bi 2 Sr 2 CaCu 2 O 8 vortex cores. We detected numerous phenomena predicted for a field-induced PDW, including two sets of particle-hole symmetric N ( r ) modulations with wave vectors Q P and 2 Q P , with the latter decaying twice as rapidly from the core as the former. These data imply that the primary field-induced state in underdoped superconducting cuprates is a PDW, with approximately eight CuO 2 unit-cell periodicity and coexisting with its secondary CDWs.