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Engineering designers often generate multiple concepts to increase novelty and diversity among early solution candidates. Many past studies have focused on creating new concepts “from scratch;” however, designers at every level become fixated on their initial designs and struggle to generate different ideas. In line with prior work on design transformations, we propose a concept generation process ofiterative transformationto create new ideas by intentionally introducing major changes in form, nature, or function to an existing concept. A study of this concept generation process recruited beginning engineering students likely to benefit from an alternative to blank slate generation. Working alone in a single test session, students generated an initial concept for a presented design problem. Then, they were instructed to generate another concept by transforming their initial design into a new concept and repeated this process to create three more concepts. In a second design round, students were asked to consider 7 Design Heuristics strategies to prompt possible transformations for their concepts. Beginning again with their initial concept, each student generated another set of four transformed concepts using iterative transformation. The analysis considered 60 initial concepts and 476 transformed concepts with and without the use of Design Heuristics. We createdDesign Transformation Diagramsto observe links (sequential, non-sequential, or both) between transformed concepts within each set of four concepts and between the two sets. Three patterns across the diagrams were identified: Fully Sequential, Sequential with Deviation, and Divergent. When aided by Design Heuristics, transformations included more non-sequential links, suggesting synthesis, refinement, and extension of other prior concepts, and resulting in more varied and distinct transformations. This iterative transformation process may support more diversity in concepts generated through a deeper exploration of related concepts without requiring an escape from the influence of existing concepts. Concept generation strategies like Design Heuristics may support engineering students as they learn to expand their early exploration of design concepts.

 

We have developed a highly efficient synthesis of linear polydicyclopentadiene (pDCPD)viaphotoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP) and investigated theT_g–M_ndependence of linear pDCPD.

 

We present a grid of stellar models at supersolar metallicity (Z = 0.020) extending the previous grids of Geneva models at solar and sub-solar metallicities. A metallicity of Z = 0.020 was chosen to match that of the inner Galactic disc. A modest increase of 43 per cent (= 0.02/0.014) in metallicity compared to solar models means that the models evolve similarly to solar models but with slightly larger mass-loss. Mass-loss limits the final total masses of the supersolar models to 35 M⊙ even for stars with initial masses much larger than 100 M⊙. Mass-loss is strong enough in stars above 20 M⊙ for rotating stars (25 M⊙ for non-rotating stars) to remove the entire hydrogen-rich envelope. Our models thus predict SNII below 20 M⊙ for rotating stars (25 M⊙ for non-rotating stars) and SNIb (possibly SNIc) above that. We computed both isochrones and synthetic clusters to compare our supersolar models to the Westerlund 1 (Wd1) massive young cluster. A synthetic cluster combining rotating and non-rotating models with an age spread between log10(age/yr) = 6.7 and 7.0 is able to reproduce qualitatively the observed populations of WR, RSG, and YSG stars in Wd1, in particular their simultaneous presence at $\log _{10}(L/\mathit {\mathrm{ L}}_{\odot })$ = 5–5.5. The quantitative agreement is imperfect and we discuss the likely causes: synthetic cluster parameters, binary interactions, mass-loss and their related uncertainties. In particular, mass-loss in the cool part of the HRD plays a key role.

 

Context. Grids of stellar models, computed with the same physical ingredients, allow one to study the impact of a given physics on a broad range of initial conditions and they are a key ingredient for modeling the evolution of galaxies. Aims. We present here a grid of single star models for masses between 0.8 and 120 M ⊙ , with and without rotation for a mass fraction of heavy element Z  = 0.006, representative of the Large Magellanic Cloud (LMC). Methods. We used the GENeva stellar Evolution Code. The evolution was computed until the end of the central carbon-burning phase, the early asymptotic giant branch phase, or the core helium-flash for massive, intermediate, and low mass stars, respectively. Results. The outputs of the present stellar models are well framed by the outputs of the two grids obtained by our group for metallicities above and below the one considered here. The models of the present work provide a good fit to the nitrogen surface enrichments observed during the main sequence for stars in the LMC with initial masses around 15 M ⊙ . They also reproduce the slope of the luminosity function of red supergiants of the LMC well, which is a feature that is sensitive to the time-averaged mass loss rate over the red supergiant phase. The most massive black hole that can be formed from the present models at Z  = 0.006 is around 55 M ⊙ . No model in the range of mass considered will enter into the pair-instability supernova regime, while the minimal mass to enter the region of pair pulsation instability is around 60 M ⊙ for the rotating models and 85 M ⊙ for the nonrotating ones. Conclusions. The present models are of particular interest for comparisons with observations in the LMC and also in the outer regions of the Milky Way. We provide public access to numerical tables that can be used for computing interpolated tracks and for population synthesis studies. 

Photo‐redox mediated ring‐opening metathesis polymerization (photo‐ROMP) is an emerging ROMP technique that uses an organic redox mediator and a vinyl ether initiator, in contrast to metal‐based initiators traditionally used in ROMP. The reversibility of the redox‐mediated initiation and propagation steps enable spatiotemporal control over the polymerization. Herein, we explore a simple, inexpensive means of controlling molecular weight, using alpha olefins as chain transfer agents. This method enables access to low molecular weight oligomers, and molecular weights between 1 and 30 kDa can be targeted simply by altering the stoichiometry of the reaction. This method of molecular weight control was then used to synthesize a functionalized norbornene copolymer in a range of molecular weights for specific materials applications.

 

Photo‐redox mediated ring‐opening metathesis polymerization (photo‐ROMP) is an emerging ROMP technique that uses an organic redox mediator and a vinyl ether initiator, in contrast to metal‐based initiators traditionally used in ROMP. The reversibility of the redox‐mediated initiation and propagation steps enable spatiotemporal control over the polymerization. Herein, we explore a simple, inexpensive means of controlling molecular weight, using alpha olefins as chain transfer agents. This method enables access to low molecular weight oligomers, and molecular weights between 1 and 30 kDa can be targeted simply by altering the stoichiometry of the reaction. This method of molecular weight control was then used to synthesize a functionalized norbornene copolymer in a range of molecular weights for specific materials applications.