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  1. Water vapor (H2O) is one of the brightest molecular emitters after carbon monoxide (CO) in galaxies with high infrared (IR) luminosity, allowing us to investigate the warm and dense phase of the interstellar medium (ISM) where star formation occurs. However, due to the complexity of its radiative spectrum, H2O is not frequently exploited as an ISM tracer in distant galaxies. Therefore, H2O studies of the warm and dense gas at high-zremain largely unexplored. In this work, we present observations conducted with the Northern Extended Millimeter Array (NOEMA) toward threez > 6 IR-bright quasarsJ2310+1855,J1148+5251, andJ0439+1634targeted in their multiple para- and ortho-H2O transitions (312 − 303, 111 − 000, 220 − 211, and 422 − 413), as well as their far-IR (FIR) dust continuum. By combining our data with previous measurements from the literature, we estimated the dust masses and temperatures, continuum optical depths, IR luminosities, and star formation rates (SFR) from the FIR continuum. We modeled the H2O lines using the MOLPOP-CEP radiative transfer code, finding that water vapor lines in our quasar host galaxies are primarily excited in the warm, dense (with a gas kinetic temperature and density ofTkin = 50 K,nH2 ∼ 104.5 − 105 cm−3) molecular medium with a water vapor column density ofNH2O ∼ 2 × 1017 − 3 × 1018 cm−3. High-JH2O lines are mainly radiatively pumped by the intense optically-thin far-IR radiation field associated with a warm dust component at temperatures ofTdust ∼ 80 − 190 K that account for < 5 − 10% of the total dust mass. In the case of J2310+1855, our analysis points to a relatively high value of the continuum optical depth at 100 μm (τ100 ∼ 1). Our results are in agreement with expectations based on the H2O spectral line energy distribution of local and high-zultra-luminous IR galaxies and active galactic nuclei (AGN). The analysis of the Boltzmann diagrams highlights the interplay between collisions and IR pumping in populating the high H2O energy levels and it allows us to directly compare the excitation conditions in the targeted quasar host galaxies. In addition, the observations enable us to sample the high-luminosity part of the H2O–total-IR (TIR) luminosity relations (LH2O − LTIR). Overall, our results point to supralinear trends that suggest H2O–TIR relations are likely driven by IR pumping, rather than the mere co-spatiality between the FIR continuum- and line-emitting regions. The observedLH2O/LTIRratios in ourz > 6 quasars do not show any strong deviations with respect to those measured in star-forming galaxies and AGN at lower redshifts. This supports the notion that H2O can be likely used to trace the star formation activity buried deep within the dense molecular clouds.

     
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  2. null (Ed.)
    We present a multiline survey of the interstellar medium (ISM) in two z  > 6 quasar host galaxies, PJ231−20 ( z  = 6.59) and PJ308−21 ( z  = 6.23), and their two companion galaxies. Observations were carried out using the Atacama Large (sub-)Millimeter Array (ALMA). We targeted 11 transitions including atomic fine-structure lines (FSLs) and molecular lines: [NII] 205 μm , [CI] 369 μm , CO ( J up  = 7, 10, 15, 16), H 2 O 3 12  − 2 21 , 3 21  − 3 12 , 3 03  − 2 12 , and the OH 163 μm doublet. The underlying far-infrared (FIR) continuum samples the Rayleigh-Jeans tail of the respective dust emission. By combining this information with our earlier ALMA [CII] 158 μm observations, we explored the effects of star formation and black hole feedback on the ISM of the galaxies using the CLOUDY radiative transfer models. We estimated dust masses, spectral indexes, IR luminosities, and star-formation rates from the FIR continuum. The analysis of the FSLs indicates that the [CII] 158 μm and [CI] 369 μm emission arises predominantly from the neutral medium in photodissociation regions (PDRs). We find that line deficits agree with those of local luminous IR galaxies. The CO spectral line energy distributions (SLEDs) reveal significant high- J CO excitation in both quasar hosts. Our CO SLED modeling of the quasar PJ231−20 shows that PDRs dominate the molecular mass and CO luminosities for J up  ≤ 7, while the J up  ≥ 10 CO emission is likely driven by X-ray dissociation regions produced by the active galactic nucleus (AGN) at the very center of the quasar host. The J up  > 10 lines are undetected in the other galaxies in our study. The H 2 O 3 21  − 3 12 line detection in the same quasar places this object on the L H 2 O  −  L TIR relation found for low- z sources, thus suggesting that this water vapor transition is predominantly excited by IR pumping. Models of the H 2 O SLED and of the H 2 O-to-OH 163 μm ratio point to PDR contributions with high volume and column density ( n H  ∼ 0.8 × 10 5 cm −3 , N H  = 10 24 cm −2 ) in an intense radiation field. Our analysis suggests a less highly excited medium in the companion galaxies. However, the current data do not allow us to definitively rule out an AGN in these sources, as suggested by previous studies of the same objects. This work demonstrates the power of multiline studies of FIR diagnostics in order to dissect the physical conditions in the first massive galaxies emerging from cosmic dawn. 
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