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This study describes computer simulations of carbonization and graphite formation, including the effects of hydrogen, nitrogen, oxygen, and sulfur. We introduce a novel technique to simulate carbonization, ‘Simulation of Thermal Emission of Atoms and Molecules (STEAM)’, designed to elucidate volatile outgassing and density variations in the intermediate material during carbonization. The investigation analyzes the functional groups that endure through high-temperature carbonization and examines the graphitization processes in carbon-rich materials containing non-carbon impurity elements. The physical, vibrational, and electronic attributes of impure amorphous graphite are analyzed, and the impact of nitrogen on electronic conduction is investigated.

 

We present photometric and spectroscopic data for SN 2022joj, a nearby peculiar Type Ia supernova (SN Ia) with a fast decline rate (Δm_15,B= 1.4 mag). SN 2022joj shows exceedingly red colors, with a value of approximatelyB−V≈ 1.1 mag during its initial stages, beginning from 11 days before maximum brightness. As it evolves, the flux shifts toward the blue end of the spectrum, approachingB−V≈ 0 mag around maximum light. Furthermore, at maximum light and beyond, the photometry is consistent with that of typical SNe Ia. This unusual behavior extends to its spectral characteristics, which initially displayed a red spectrum and later evolved to exhibit greater consistency with typical SNe Ia. Spectroscopically, we find strong agreement between SN 2022joj and double detonation models with white dwarf masses of around 1M_⊙and a thin He shell between 0.01 and 0.05M_⊙. Moreover, the early red colors are explained by line-blanketing absorption from iron peak elements created by the double detonation scenario in similar mass ranges. The nebular spectra in SN 2022joj deviate from expectations for double detonation, as we observe strong [Feiii] emission instead of [Caii] lines as anticipated, though this is not as robust a prediction as early red colors and spectra. The fact that as He shells get thinner these SNe start to look more like normal SNe Ia raises the possibility that this is the triggering mechanism for the majority of SNe Ia, though evidence would be missed if the SNe are not observed early enough.

 

Background The distribution of resources can affect animal range sizes, which in turn may alter infectious disease dynamics in heterogenous environments. The risk of pathogen exposure or the spatial extent of outbreaks may vary with host range size. This study examined the range sizes of herbivorous anthrax host species in two ecosystems and relationships between spatial behavior and patterns of disease outbreaks for a multi-host environmentally transmitted pathogen. Methods We examined range sizes for seven host species and the spatial extent of anthrax outbreaks in Etosha National Park, Namibia and Kruger National Park, South Africa, where the main host species and numbers of cases differ. We evaluated host range sizes using the local convex hull method at different temporal scales, within-individual temporal range overlap, and relationships between ranging behavior and species contributions to anthrax cases in each park. We estimated the spatial extent of annual anthrax mortalities and evaluated whether the extent was correlated with case numbers of a given host species. Results Range size differences among species were not linearly related to anthrax case numbers. In Kruger the main host species had small range sizes and high range overlap, which may heighten exposure when outbreaks occur within their ranges. However, different patterns were observed in Etosha, where the main host species had large range sizes and relatively little overlap. The spatial extent of anthrax mortalities was similar between parks but less variable in Etosha than Kruger. In Kruger outbreaks varied from small local clusters to large areas and the spatial extent correlated with case numbers and species affected. Case numbers of secondary host species with larger range sizes were positively correlated with the spatial extent of outbreaks in both parks. Conclusions Our results provide new information on the spatiotemporal structuring of ranging movements of anthrax host species in two ecosystems. The results linking anthrax dynamics to host space use are correlative, yet suggest that, though partial and proximate, host range size and overlap may be contributing factors in outbreak characteristics for environmentally transmitted pathogens. 

Invasive species alter invaded ecosystems via direct impacts such as consumption. In turn, an invasive species’ ability to thrive in new habitats depends on its ability to exploit available resources, which may change over time and space. Diet quality and quantity are indicators of a consumer’s consumptive effects and can be strongly influenced by season and latitude. We examined the effects of season and latitude on the diet quality and quantity of the invasive Asian shore crab Hemigrapsus sanguineus throughout a non-winter sampling year at 5 different sites spanning 8° of latitude across its invaded United States range. We found that diet quality, averaged through time, largely follows an expected latitudinal cline, being higher in the center of its range and lower toward the southern and northern edges. We also found that while some sites show similar patterns of diet quality variation with season, no pattern is consistent across all latitudes. Finally, we found that crabs at sites with low diet quality during summer reproductive months did not compensate by increasing total consumption. Because the Asian shore crab is an important consumer in its invaded ecosystems, understanding how its diet quality and quantity vary with season and latitude can help us better understand how this species influences trophic interactions and community structure, how it has been able to establish across a wide ecological and environmental range, and where future range expansion is most likely to occur. 

In high energy physics (HEP), analysis metadata comes in many forms—from theoretical cross-sections, to calibration corrections, to details about file processing. Correctly applying metadata is a crucial and often time-consuming step in an analysis, but designing analysis metadata systems has historically received little direct attention. Among other considerations, an ideal metadata tool should be easy to use by new analysers, should scale to large data volumes and diverse processing paradigms, and should enable future analysis reinterpretation. This document, which is the product of community discussions organised by the HEP Software Foundation, categorises types of metadata by scope and format and gives examples of current metadata solutions. Important design considerations for metadata systems, including sociological factors, analysis preservation efforts, and technical factors, are discussed. A list of best practices and technical requirements for future analysis metadata systems is presented. These best practices could guide the development of a future cross-experimental effort for analysis metadata tools.

 

Foundational engineering courses are critical to student success in engineering programs. The conceptually challenging content of these courses establishes the requisite knowledge for future classes. Thus, it is no surprise that such courses can serve as barriers or gatekeepers to successful student progress through the undergraduate curriculum. Although the difficulty of the courses may be necessary, often other features of the course delivery such as large class environments or a few very high-stakes assessments can further exacerbate these challenges. And especially problematic, past studies have shown that grade penalties associated with these courses and environments may disproportionately impact women. On the faculty side, institutions often turn to non-tenure track instructional faculty to teach multiple sections of foundational courses each semester. Although having faculty whose sole role is dedicated to quality teaching is an asset, benefits would likely be maximized when such faculty have clear metrics for paths to promotion, some autonomy and ownership regarding the curriculum, and overall job satisfaction. However, literature suggests that faculty, like students, note ill effects from large classes, such as challenges connecting and building rapport with students and having time to offer individualized feedback to students. Our NSF IUSE project focuses on instructors of large foundational engineering students with the belief that by better understanding the educational environment from their perspective we can improve the quality of the teaching and learning environment for all engineering students. Our project regularly convenes faculty teaching an array of core courses (e.g,. Mathematics, Chemistry, Mechanics, Physics) and uses insights from these meetings and individual interviews to identify possible leverage points where our project or the institution more broadly might affect change. Parallel to this effort, we have been working with data stewards on campus to gain access to institutional data (e.g., student course and grade histories, student evaluations of faculty teaching) to link and provide aggregate deidentified results to faculty to feed more information in to their decision-making. We are demonstrating that regular engagement between faculty and institutional leaders around analyzed and curated data is essential to continuous and systematic improvement. Efforts to date have included building an institutional data explorer dashboard (e.g., influences of pre-requisite courses on future courses) and drafting reports to be sent to department heads and associate deans which gather priorities identified in the first year of our research. For example, participating instructors identified that clarity of promotion paths across non-tenure track teaching faculty from different departments varied greatly, and the institution as a whole could benefit from clarified university-wide guidance. While some findings may be institution-specific (NSF IUSE Institutional Transformation track), as a large public research institution, peer-institutions with high engineering enrollments often face similar challenges and so findings from our change efforts potentially have broad applicability.