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  1. Abstract High-resolution passive seismic imaging of shallow subsurface structures is often challenged by the scarcity of coherent body-wave energy in ambient noise recorded at surface stations. We show that the autocorrelation (AC) of teleseismic P-wave coda extracted from just one month of continuous recording at 5 Hz geophones can overcome this limitation. We apply this method to investigate the longitudinal subsurface bedrock structure of Unaweep Canyon—a paleovalley in western Colorado (United States) with complex evolution. Both fluvial and glacial processes have been proposed to explain the canyon’s genesis and morphology. The teleseismic P-wave coda AC retrieves zero-offset reflections from the shallow (200–500 m depth) basement interface at 120 stations along a 5 km long profile. In addition, we invert interferometrically retrieved surface-wave dispersion for the shear-wave structure of the sedimentary fill. Combined interpretation of these results and other geophysical and well data suggests an overdeepened basement geometry most consistent with glacial processes. 
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  2. Abstract Paleo-loess and silty eolian-marine strata are well recognized across the Carboniferous-Permian of equatorial Pangaea. Eolian-transported dust and loess appear in the late Devonian in the west, are common by the Late Carboniferous, and predominate across equatorial Pangaea by the Permian. The thickest loess deposits in Earth history –>1000 m− date from this time, and archive unusually dusty equatorial conditions, especially compared to the dearth of equatorial dust in the Cenozoic. Loess archives a confluence of silt generation, eolian emission and transport, and ultimate accumulation in dust traps that included ephemerally wet surfaces and epeiric seas. Orogenic belts sourced the silt, and mountain glaciation may have exacerbated voluminous silt production, but remains controversial. In western Pangaea, large rivers transported silt westward, and floodplain deflation supplied silt for loess and dust. Expansion of dust deposition in Late Pennsylvanian time records aridification that progressed across Pangaea, from west to east. Contemporaneous volcanism may have created acidic atmospheric conditions to enhance nutrient reactivity of dusts, affecting Earth’s carbon cycle. The late Paleozoic was Earth’s largest and most long-lived dust bowl, and this dust represents both an archive and agent of climate and climate change. Supplementary material at https://doi.org/10.6084/m9.figshare.c.6299508 
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  3. Earth has sustained continental glaciation several times in its past. Because continental glaciers ground to low elevations, sedimentary records of ice contact can be preserved from regions that were below base level, or subject to subsidence. In such regions, glaciated pavements, ice-contact deposits such as glacial till with striated clasts, and glaciolacustrine or glaciomarine strata with dropstones reveal clear signs of former glaciation. But assessing upland (mountain) glaciation poses particular challenges because elevated regions typically erode, and thus have extraordinarily poor preservation potential. Here we propose approaches for detecting the former presence of glaciation in the absence or near-absence of ice-contact indicators; we apply this specifically to the problem of detecting upland glaciation, and consider the implications for Earth’s climate system. Where even piedmont regions are eroded, pro- and periglacial phenomena will constitute the primary record of upland glaciation. Striations on large (pebble and larger) clasts survive only a few km of fluvial transport, but microtextures developed on quartz sand survive longer distances of transport, and record high-stress fractures consistent with glaciation. Proglacial fluvial systems can be difficult to distinguish from non-glacial systems, but a preponderance of facies signaling abundant water and sediment, such as hyperconcentrated flood flows, non-cohesive fine-grained debris flows, and/or large-scale and coarse-grained cross-stratification are consistent with proglacial conditions, especially in combination with evidence for cold temperatures, such as rip-up clasts composed of noncohesive sediment, indicating frozen conditions, and/or evidence for a predominance of physical over chemical weathering. Other indicators of freezing (periglacial) conditions include frozen-ground phenomena such as fossil ice wedges and ice crystals. Voluminous loess deposits and eolian-marine silt/mudstone characterized by silt modes, a significant proportion of primary silicate minerals, and a provenance from non-silt precursors can indicate the operation of glacial grinding, even though such deposits may be far removed from the site(s) of glaciation. Ultimately, in the absence of unambiguous ice-contact indicators, inferences of glaciation must be grounded on an array of observations that together record abundant meltwater, temperatures capable of sustaining glaciation, and glacial weathering (e.g., glacial grinding). If such arguments are viable, they can bolster the accuracy of past climate models, and guide climate modelers in assessing the types of forcings that could enable glaciation at elevation, as well as the extent to which (extensive) upland glaciation might have influenced global climate. 
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  4. Abstract Delicate impressions in lacustrine strata of the lower Permian (lower Cisuralian) Usclas Formation record ephemeral freezing in equatorial Pangea. These sediments accumulated in the paleoequatorial and intramontane Lodève Basin (southern Massif Central, France) during peak icehouse conditions of the Late Paleozoic Ice Age. Experimental replication of these features supports the interpretation that they are ice-crystal molds. Evidence for films of ice in marginal-lacustrine sediment at such low latitudes and inferred low to moderate altitudes (1–2 km) calls for a reevaluation of climate conditions in eastern equatorial Pangea. Ephemeral freezing implies either cold tropical temperatures (~5 °C cooler than the Last Glacial Maximum) and/or lapse rates that exceeded those of the Last Glacial Maximum. Extreme continentality of the Lodève Basin would have amplified seasonality, albeit the climatic forcing(s) necessary to have promoted cold temperatures in equatorial Pangea remain enigmatic. 
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  5. Abstract

    The cryosphere hosts a widespread microbial community, yet microbial influences on silicate weathering have been historically neglected in cold‐arid deserts. Here we investigate bioweathering by a cold‐tolerant cyanobacteria (Leptolyngbya glacialis) via laboratory experiments using glaciofluvial drift sediments at 12°C, analogous to predicted future permafrost surface temperatures. Our results show threefold enhanced Si weathering rates in pre‐weathered, mixed‐lithology Antarctic biotic reactors compared to abiotic controls, indicating the significant influence of microbial life on weathering. Although biotic and abiotic weathering rates are similar in Icelandic sediments, neo‐formed clay and Fe‐(oxy)hydroxide minerals observed in association with biofilms in biotic reactors are common on Icelandic mafic minerals, similar to features observed in unprocessed Antarctic drifts. This suggests that microbes enhance weathering in systems where they must scavenge for nutrients that are not easily liberated via abiotic pathways; potential biosignatures may form in nutrient‐rich systems as well. In both sediment types we also observed up to fourfold higher bicarbonate concentrations in biotic reactors relative to abiotic reactors, indicating that, as warming occurs, psychrotolerant biota will enhance bicarbonate flux to the oceans, thus stimulating carbonate deposition and providing a negative feedback to increasing atmospheric CO2.

     
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    Abstract Carboniferous–Permian strata in basins within the Central Pangean Mountains in France archive regional paleoequatorial climate during a unique interval in geological history (Pangea assembly, ice-age collapse, megamonsoon inception). The voluminous (∼1.5 km) succession of exclusively fine-grained red beds that comprises the Permian Salagou Formation (Lodève Basin, France) has long been interpreted to record either lacustrine or fluvial deposition, primarily based on a local emphasis of subaqueous features in the upper ∼25% of the section. In contrast, data presented here indicate that the lower-middle Salagou Formation is dominated by up to 15-m-thick beds of internally massive red mudstone with abundant pedogenic features (microscale) and no evidence of channeling. Up-section, limited occurrences of ripple and hummocky cross-stratification, and mudcracks record the intermittent influence of shallow water, but with no channeling nor units with grain sizes exceeding coarse silt. These data suggest that the most parsimonious interpretation for the Salagou Formation involves eolian transport of the sediment and ultimate deposition as loess in shallow, ephemeral lacustrine environments. Provenance analyses of the Salagou Formation indicate coarse-grained protoliths and, together with geochemical proxies (chemical index of alteration [CIA] and τNa) that correspond respectively to a low degree of chemical weathering and a mean annual temperature of ∼4 °C, suggest that silt generation in this case is most consistent with cold-weathering (glacial and associated periglacial) processes in the Variscan highlands. Together with previous studies that detailed voluminous Permian loess in western equatorial Pangea, this work shows a globally unique distribution of dust at low latitudes that can be linked either directly to glaciated alpine terranes or to reworked and deflated deposits of other types (e.g., fluvial outwash) where fine-grained material was originally generated from glacial grinding in alpine systems. These results further support a revised model for early Permian climate, in which extratropical ice sheets coexisted with a semiarid tropics that may have hosted significant ice at moderate elevation. 
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  9. Abstract

    An imbalance in pyrite weathering and burial is a primary mechanism responsible for oxygenation of the atmosphere and oceans, but key processes governing the terrestrial sulfur cycle remain nebulous. Here, we investigate components of the terrestrial sulfur cycle in a highly productive, glacier‐fed catchment, and use a global mass balance model to constrain riverine sulfur fluxes. Chemistry of stream water and plant debris in the Jostedal watershed, Norway suggests sulfur isotope discrimination is occurring in the porewater. Global models also corroborate additional, previously overlooked pyrite burial with a modest isotope fractionation (<20‰), similar to values reported from freshwater ecosystems. Collectively, our results indicate that a significant amount of sulfate produced by weathering remains trapped in terrestrial environments. This terrestrial sulfur sink might have waxed and waned over geologic time in response to major biogeochemical events such as terrestrial afforestation.

     
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