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ABSTRACT Spectral lines from formaldehyde (H2CO) molecules at cm wavelengths are typically detected in absorption and trace a broad range of environments, from diffuse gas to giant molecular clouds. In contrast, thermal emission of formaldehyde lines at cm wavelengths is rare. In previous observations with the 100 m Robert C. Byrd Green Bank Telescope (GBT), we detected 2 cm formaldehyde emission towards NGC 7538 IRS1 – a high-mass protostellar object in a prominent star-forming region of our Galaxy. We present further GBT observations of the 2 and 1 cm H2CO lines to investigate the nature of the 2 cm H2CO emission. We conducted observations to constrain the angular size of the 2 cm emission region based on a East–West and North–South cross-scan map. Gaussian fits of the spatial distribution in the East–West direction show a deconvolved size (at half maximum) of the 2 cm emission of 50 arcsec ± 8 arcsec. The 1 cm H2CO observations revealed emission superimposed on a weak absorption feature. A non-LTE radiative transfer analysis shows that the H2CO emission is consistent with quasi-thermal radiation from dense gas (${\sim}10^5$–$10^6$ cm−3). We also report detection of four transitions of CH3OH (12.2, 26.8, 28.3, 28.9 GHz), the (8,8) transition of NH3 (26.5 GHz), and a cross-scan map of the 13 GHz SO line that shows extended emission (>50 arcsec). 

We report on one of the highest sensitivity surveys for molecular lines in the frequency range 6.0 to 7.4 GHz conducted to date. The observations were done with the 305m Arecibo Telescope toward a sample of twelve intermediate/high-mass star forming regions. We searched for a large number of transitions of different molecules, including CH3OH and OH. The low RMS noise of our data (~5 mJy for most sources and transitions) allowed detection of spectral features that have not been seen in previous lower sensitivity observations of the sources, such as detection of excited OH and 6.7 GHz CH3OH absorption. A review of 6.7 GHz CH3OH detections indicates an association between absorption and radio continuum sources in high-mass star forming regions, although selection biases in targeted projects and low sensitivity of blind surveys imply incompleteness. Absorption of excited OH transitions was also detected toward three sources. In particular, we confirm a broad 6.035 GHz OH absorption feature in G34.26+0.15 characterized by an asymmetric blue-shifted wing indicative of expansion, perhaps a large scale outflow in this HII region.