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Archived water quality data collected between 1901 and 2019 were used to reconstruct annual averages of various forms of C, N, P, and silicate concentrations and alkalinity in the lower Mississippi River. During this interval the average annual nitrate concentrations doubled pre-dominantly from fertilizer applications and tiling, silicate concentrations decreased by half as diatom sedimentation increased as dams were built, and alkalinity increased 16%. Variances in silicate concentrations were proportional to river discharge before 1980 and concentrations have been stable since then. Average annual temperatures, discharge and alkalinity increased simultaneously around 1980; this suggests that there was greater weathering thereafter and is supported by the positive relationships between variations in alkalinity and variations in nitrate, phosphate, and silicate concentrations. The conversion of forests and grasslands into farmlands and improved drainage resulted in less evapotranspiration, a higher percent of precipitation going into streams and altered soil water bio-geo-chemistries. Field trials demonstrating soil health improvements resulting from more live roots and soil cover and greater biodiversity demonstrate water quality improvements and no effect on farm profitability. Lowering nitrate loading to the coastal waters will reduce summertime hypoxic waters formation offshore, but alkalinity in the river will increase further with climate warming.

 

The intersection between the Mid-Atlantic Ridge and Iceland hotspot provides a natural laboratory where the composition and dynamics of Earth’s upper mantle can be observed. Plume-ridge interaction drives variations in the melting regime, which result in a range of crustal types, including a series of V-shaped ridges and V-shaped troughs south of Iceland. Expedition 395 has three objectives: (1) to test contrasting hypotheses for the formation of V-shaped ridges, (2) to understand temporal changes in ocean circulation and explore connections with plume activity, and (3) to reconstruct the evolving chemistry of hydrothermal fluids with increasing crustal age and varying sediment thickness and crustal architecture. After being postponed from summer 2020 due to the COVID-19 pandemic, the drilling objectives of Expedition 395 were partially completed without a science party on board during Expedition 395C in summer 2021, when basalt cores were collected at four sites (U1554, U1555, U1562, and U1563). Sediment cores were collected from these sites, as well as from Site U1564, and casing was installed to 602 meters below seafloor at Site U1554. Expedition 395 is scheduled with sufficient time to complete the planned operations remaining at Sites U1564 and U1554, leaving approximately 22 operating days available for other sites, including a new proposed site, REYK-14B, which is located west of Reykjanes Ridge on the Eirik drift. This addendum provides the operations plan for rescheduled Expedition 395, including details of the additional site. 

Total ammonia (TA) concentrations (NH_{3 +}NH₄⁺) at four locations at the terminal end of the Mississippi River, the largest river on the North American continent, were assembled to examine trends and relationships with point and non-point loadings from 1980 to 2019 and compared to values in 1900 to 1901. TA concentrations were lowest in 1900 to 1901, highest in 1980 and then declined, and then rose slightly in the last 2 decades. Variations in individual measurements and in situ temperature are indirectly related because of the influence temperature has on ammonia solubility and protein degradation rates. Importantly, the average annual concentrations of TA were directly related to both total coliform and fecal coliform densities. The highest measured average annual TA concentrations in the river (15.5 ± 1.5 SE µmol in 1985) were below the currently recommended toxicity thresholds for freshwater aquatic ecosystems. Sewerage loadings are implicated as controlling factors on TA concentrations, not nitrogen stabilizers added to fertilizers to reduce ammonia conversion to nitrate, nor the fertilizer loadings.

 

This paper provides an overview of the MDaS S-STEM scholarship program. With the growing need for professionals with technology and critical thinking skills related to data analysis, the MDaS program employs established recruitment and retention activities for undergraduates in STEM fields, to encourage consideration of careers in data science related fields. The purpose of the program is to provide financial and professional support to low-income and underrepresented STEM students to improve their chances of completing degrees related to data science. This paper presents the motivation for the program, its goals, structure, research questions, and the design and implementation of its bootcamp cohort building component for engaging students. The results and experiences related to its first year of operation are presented. 

The five primary sites proposed for International Ocean Discovery Program (IODP) Expedition 395, which was postponed because of the COVID-19 pandemic, were cored during IODP Expedition 395C. The Expedition 395C operations, shipboard measurements, and sampling were adjusted to account for the absence of a sailing science party. The Expedition 395/395C objectives are (1) to investigate temporal variations in ocean crust generation at the Reykjanes Ridge and test hypotheses for the influence of Iceland mantle plume fluctuations on these processes, (2) to analyze sedimentation rates at the Björn and Gardar contourite drifts, as proxies for Cenozoic variations of North Atlantic deepwater circulation, and for uplift and subsidence of the Greenland-Scotland Ridge gateway related to plume activity, and (3) to analyze the alteration of oceanic crust and its interaction with seawater and sediments. During Expedition 395C, basalt cores were collected at four sites: U1554, U1555, U1562, and U1563. Sediment cores were also collected from these sites as well as from Site U1564, and casing was installed to 602 m at Site U1554. The amount of recovered cores, their preliminary descriptions, and the analyses of shipboard samples show that the results of Expedition 395C will fulfill a significant part of the Expedition 395 objectives. Basalts were collected from two V-shaped ridge and trough pairs, which will allow the investigation of the variability in mantle source and temperature causing this ridge/trough pattern. Basalt cores span an expected age range of 2.8–13.9 Ma, which will allow us to investigate the hydrothermal weathering processes. Sediments from the Björn drift were cored to basement, along with the uppermost 600 m of sediments from the Gardar drift. The data provided by Expedition 395C are a major advancement in achieving the work of Expedition 395. 

Salinity control, nutrient additions, and sediment supply were directly or indirectly the rationale for a $220 million coastal wetland restoration project (Davis Pond River Diversion) that began in 2002. We sampled Mississippi River water going in and out of the receiving basin from 1999 to 2018 to understand why wetland loss increased after it began. There was a reduction in inorganic sediments, nitrogen (N), and phosphorus (P) concentrations within the ponding area of 77%, 39% and 34%, respectively, which is similar to that in other wetlands. But the average sediment accumulation of 0.6 mm year⁻¹inadequately balances the present-day 5.6 mm year⁻¹sea level rise or the 7.9 ± 0.13 mm year⁻¹accretion rates in these organic soils. Nutrients added likely reduced live belowground biomass and soil strength, and increased decomposition of the organic matter necessary to sustain elevations. The eutrophication of the downstream aquatic system from the diversion, principally by P additions, increased Chlaconcentrations to a category of ‘poor’ water quality. We conclude that this diversion, if continued, will be a negative influence on wetland area and will eutrophy the estuary. It is a case history example for understanding the potential effects arising from proposed river diversions.

 

Seismicity along mid‐ocean ridges and oceanic transform faults provides insights into the processes of crustal accretion and strike‐slip deformation. In the equatorial Atlantic ocean, the slow‐spreading Mid‐Atlantic Ridge is offset by some of the longest‐offset transform faults on Earth, which remain relatively poorly understood due to its remote location far from land‐based teleseismic receivers. A catalog of T‐phase events detected by an array of 10 autonomous hydrophones deployed between 2011 and 2015, extending from 20°N to 10°S is presented. The final catalog of 6,843 events has a magnitude of completeness of 3.3, compared to 4.4 for the International Seismic Center teleseismic catalog covering the same region, and allows investigation of the dual processes of crustal accretion and transform fault slip. The seismicity rate observed at asymmetric spreading segments (those hosting detachment faults) is significantly higher than that of symmetric spreading centers, and 74% of known hydrothermal vents along the equatorial Mid‐Atlantic Ridge occur on asymmetric spreading segments. Aseismic patches are present on nearly all equatorial Atlantic transform faults, including on the Romanche transform where regional rotation and transpression could explain both bathymetric uplift and reduction in seismic activity. The observed patterns in seismicity provide insight into the thermal and mechanical structure of the ridge axis and associated transform faults, and potentially provide a method for investigating the distribution of hydrothermal vent systems.

 

Recently, the region surrounding eHWC J1842−035 has been studied extensively by γ-ray observatories due to its extended emission reaching up to a few hundred TeV and potential as a hadronic accelerator. In this work, we use 1910 days of cumulative data from the High Altitude Water Cherenkov (HAWC) observatory to carry out a dedicated systematic source search of the eHWC J1842−035 region. During the search, we found three sources in the region, namely, HAWC J1844−034, HAWC J1843−032, and HAWC J1846−025. We have identified HAWC J1844−034 as the extended source that emits photons with energies up to 175 TeV. We compute the spectrum for HAWC J1844−034, and by comparing with the observational results from other experiments, we have identified HESS J1843−033, LHAASO J1843−0338, and TASG J1844−038 as very-high-energy γ-ray sources with a matching origin. Also, we present and use the multiwavelength data to fit the hadronic and leptonic particle spectra. We have identified four pulsar candidates in the nearby region in which PSR J1844−0346 is found to be the most likely candidate due to its proximity to HAWC J1844−034 and the computed energy budget. We have also found SNR G28.6−0.1 as a potential counterpart source of HAWC J1844−034 for which both leptonic and hadronic scenarios are feasible.

 

The intersection between the Mid-Atlantic Ridge and Iceland hotspot provides a natural laboratory where the composition and dynamics of Earth’s upper mantle can be observed. Plume-ridge interaction drives variations in the melting regime, which result in a range of crustal types, including a series of V-shaped ridges (VSRs) and V-shaped troughs (VSTs) south of Iceland. Time-dependent mantle upwelling beneath Iceland dynamically supports regional bathymetry and leads to changes in the height of oceanic gateways, which in turn control the flow of deep water on geologic timescales. Expedition 395 has three objectives: (1) to test contrasting hypotheses for the formation of VSRs, (2) to understand temporal changes in ocean circulation and explore connections with plume activity, and (3) to reconstruct the evolving chemistry of hydrothermal fluids with increasing crustal age and varying sediment thickness and crustal architecture. This expedition will recover basaltic samples from crust that is blanketed by thick sediments and is thus inaccessible when using dredging. Major, trace, and isotope geochemistry of basalts will allow us to observe spatial and temporal variations in mantle melting processes. We will test the hypothesis that the Iceland plume thermally pulses on two timescales (5–10 and ~30 Ma), leading to fundamental changes in crustal architecture. This idea will be tested against alternative hypotheses involving propagating rifts and buoyant mantle upwelling. Millennial-scale paleoclimate records are contained in rapidly accumulated sediments of contourite drifts in this region. The accumulation rate of these sediments is a proxy for current strength, which is moderated by dynamic support of oceanic gateways such as the Greenland-Scotland Ridge. These sediments also provide constraints for climatic events including Pliocene warmth, the onset of Northern Hemisphere glaciation, and abrupt Late Pleistocene climate change. Our combined approach will explore relationships between deep Earth processes, ocean circulation, and climate. Our objectives will be addressed by recovering sedimentary and basaltic cores, and we plan to penetrate ~130 m into igneous basement at five sites east of Reykjanes Ridge. Four sites intersect VSR/VST pairs, one of which coincides with Björn drift. A fifth site is located over 32.4 My old oceanic crust that is devoid of V-shaped features. This site was chosen because it intersects Oligocene–Miocene sediments of Gardar drift. Recovered sediments and basalts will provide a major advance in our understanding of mantle dynamics and the linked nature of Earth’s interior, oceans, and climate. 

At slow-spreading ridges, plate separation is commonly partly accommodated by slip on long-lived detachment faults, exposing upper mantle and lower crustal rocks on the seafloor. However, the mechanics of this process, the subsurface structure, and the interaction of these faults remain largely unknown. We report the results of a network of 56 ocean-bottom seismographs (OBSs), deployed in 2016 at the Mid-Atlantic Ridge near 13°N, that provided dense spatial coverage of two adjacent detachment faults and the intervening ridge axis. Although both detachments exhibited high levels of seismicity, they are separated by an ~8-km-wide aseismic zone, indicating that they are mechanically decoupled. A linear band of seismic activity, possibly indicating magmatism, crosscuts the 13°30′N domed detachment surface, confirming previous evidence for fault abandonment. Farther south, where the 2016 OBS network spatially overlapped with a similar survey done in 2014, significant changes in the patterns of seismicity between these surveys are observed. These changes suggest that oceanic detachments undergo previously unobserved cycles of stress accumulation and release as plate spreading is accommodated.