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The western South Atlantic Ocean has not been drilled since the end of the Deep Sea Drilling Program, leading to a dearth of sedimentary sequences available from this sector of the Atlantic Ocean. In 2020–2022, a transect of new sites was drilled during International Ocean Discovery Program Expeditions 390C, 395E, 390, and 393 at 31°S and spanning from 28.8°W to 15.2°W. Here, we use X-ray fluorescence data, combined with shipboard magnetic susceptibility and natural gamma radiation, to characterize the sediments below the oligotrophic South Atlantic Gyre at Site U1583. These geochemical data add to the otherwise understudied southwest Atlantic Ocean. 

Marine gateways play a critical role in the exchange of water, heat, salt, and nutrients between oceans and seas. The advection of dense waters helps drive global thermohaline circulation, and because the ocean is the largest of the rapidly exchanging CO2 reservoirs, this advection also affects atmospheric carbon concentration. Changes in gateway geometry can therefore significantly alter both the pattern of global ocean circulation and associated heat transport and climate, as well as having a profound local impact. Today, the volume of dense water supplied by Atlantic–Mediterranean exchange through the Gibraltar Strait is amongst the largest in the global ocean. For the past 5 My, this overflow has generated a saline plume at intermediate depths in the Atlantic that deposits distinctive contouritic sediments in the Gulf of Cadiz and contributes to the formation of North Atlantic Deep Water. This single gateway configuration only developed in the early Pliocene, however. During the Miocene, a wide, open seaway linking the Mediterranean and Atlantic evolved into two narrow corridors: one in northern Morocco, the other in southern Spain. Formation of these corridors permitted Mediterranean salinity to rise and a new, distinct, dense water mass to form and overspill into the Atlantic for the first time. Further restriction and closure of these connections resulted in extreme salinity fluctuations in the Mediterranean, leading to the formation of the Messinian Salinity Crisis salt giant. Investigating Miocene Mediterranean–Atlantic Gateway Exchange (IMMAGE) is an amphibious drilling proposal designed to recover a complete record of Atlantic–Mediterranean exchange from its Late Miocene inception to its current configuration. This will be achieved by targeting Miocene offshore sediments on either side of the Gibraltar Strait during International Ocean Discovery Program (IODP) Expedition 401 and recovering Miocene core from the two precursor connections now exposed on land with future International Continental Scientific Drilling Program (ICDP) campaigns. The scientific aims of IMMAGE are to constrain quantitatively the consequences for ocean circulation and global climate of the inception of Atlantic–Mediterranean exchange, to explore the mechanisms for high-amplitude environmental change in marginal marine systems, and to test physical oceanographic hypotheses for extreme high-density overflow dynamics that do not exist in the world today on this scale. 

This presentation will describe conditions for the use of oxygen as a reagent for the selective cleavage of thermoset composites. Carbon fiber-reinforced polymer (CFRP) composites have a prominent role in aviation, sporting goods, marine, and other manufacturing sectors and are accumulating en masse as waste, both at end-of-life and as manufacturing defects. We have recently introduced a method to use oxygen itself along with an appropriate catalyst selectively to disassemble such fully-cured composite wastes to recover both ordered carbon fiber sheets and organic materials suitable for re-manufacturing of second-life resin systems. 

The low-J rotational transitions of 12CO are commonly used to trace the distribution of molecular gas in galaxies. Their ratios are sensitive to excitation and physical conditions in the molecular gas. Spatially resolved studies of CO ratios are still sparse and affected by flux calibration uncertainties, especially since most do not have high angular resolution or do not have short-spacing information and hence miss any diffuse emission. We compare the low-J CO ratios across the disc of two massive, star-forming spiral galaxies NGC 2903 and NGC 3627 to investigate whether and how local environments drive excitation variations at GMC scales. We use Atacama Large Millimeter Array (ALMA) observations of the three lowest-J CO transitions at a common angular resolution of 4 arcsec (190 pc). We measure median line ratios of $R_{21}=0.67^{+0.13}_{-0.11}$, $R_{32}=0.33^{+0.09}_{-0.08}$, and $R_{31}=0.24^{+0.10}_{-0.09}$ across the full disc of NGC 3627. We see clear CO line ratio variation across the galaxy consistent with changes in temperature and density of the molecular gas. In particular, towards the centre, R21, R32, and R31 increase by 35  per cent, 50  per cent, and 66  per cent, respectively, compared to their average disc values. The overall line ratio trends suggest that CO(3–2) is more sensitive to changes in the excitation conditions than the two lower J transitions. Furthermore, we find a similar radial R32 trend in NGC 2903, albeit a larger disc-wide average of $\langle R_{32}\rangle =0.47^{+0.14}_{-0.08}$. We conclude that the CO low-J line ratios vary across environments in such a way that they can trace changes in the molecular gas conditions, with the main driver being changes in temperature.

 

Nitrogen hydrides such as NH3 and N2H+ are widely used by Galactic observers to trace the cold dense regions of the interstellar medium. In external galaxies, because of limited sensitivity, HCN has become the most common tracer of dense gas over large parts of galaxies. We provide the first systematic measurements of N2H+ (1-0) across different environments of an external spiral galaxy, NGC 6946. We find a strong correlation (r > 0.98, p < 0.01) between the HCN (1-0) and N2H+ (1-0) intensities across the inner ∼8 kpc of the galaxy, at kiloparsec scales. This correlation is equally strong between the ratios N2H+ (1-0)/CO (1-0) and HCN (1-0)/CO (1-0), tracers of dense gas fractions (fdense). We measure an average intensity ratio of N2H+ (1-0)/HCN (1-0) = 0.15 ± 0.02 over our set of five IRAM-30m pointings. These trends are further supported by existing measurements for Galactic and extragalactic sources. This narrow distribution in the average ratio suggests that the observed systematic trends found in kiloparsec-scale extragalactic studies of fdense and the efficiency of dense gas (SFEdense) would not change if we employed N2H+ (1-0) as a more direct tracer of dense gas. At kiloparsec scales our results indicate that the HCN (1-0) emission can be used to predict the expected N2H+ (1-0) over those regions. Our results suggest that, even if HCN (1-0) and N2H+ (1-0) trace different density regimes within molecular clouds, subcloud differences average out at kiloparsec scales, yielding the two tracers proportional to each other. 

The South Atlantic Transect (SAT) is a multidisciplinary scientific ocean drilling project that will recover complete sedimentary sections and the upper ~250 m of the underlying oceanic crust along a slow/intermediate spreading rate Mid-Atlantic Ridge crustal flow line at ~31°S. These cores were originally scheduled to be collected during International Ocean Discovery Program (IODP) Expeditions 390 and 393 in October–December 2020 and April–June 2021, respectively. In 2020 and 2021, the global COVID-19 pandemic resulted in the postponement of several IODP expeditions, including Expeditions 390 and 393, chiefly because science parties were unable to travel to the R/V JOIDES Resolution. In response, the ship was used to conduct preparatory work for the postponed expeditions that did not require a science party aboard but could be carried out by the ship’s crew and a team of technicians from the JOIDES Resolution Science Operator. Two of these expeditions (390C and 395E) were in service of the SAT drilling project, to reduce the operational risks and expedite basement drilling during the rescheduled Expeditions 390 and 393. Expeditions 390C and 395E visited five of the six primary SAT sites and successfully cored a single advanced piston corer/extended core barrel hole penetrating the entire sediment section and <10 m into the underlying basalt before installing a reentry system in a second hole at each site visited. Given these accomplishments, the operations plans for the rescheduled Expeditions 390 and 393 have been revised. 

International Ocean Discovery Program (IODP) Expeditions 390C and 395E were implemented in response to the global COVID-19 pandemic and occupied sites proposed for the postponed Expeditions 390 and 393, South Atlantic Transect 1 and 2. Expedition 395E completed most of the preparatory work that Expedition 390C did not have time to complete. The overall objective of Expeditions 390C and 395E was to core one hole at each of the South Atlantic Transect sites with the advanced piston corer/extended core barrel (APC/XCB) system to basement for gas safety monitoring and to install a reentry system with casing through the sediment to a few meters into basement in a second hole. Expedition 395E started in Cape Town, South Africa, and ended in Reykjavík, Iceland, after 20 days of on-site operations. We cored to basement at two new sites, U1560 and U1561, and completed reentry systems at three sites, U1556, U1557, and U1560. These operations will expedite basement drilling during the rescheduled Expeditions 390 and 393. Hole U1560A (Proposed Site SATL-25A) lies in ~15.2 Ma crust and is composed of carbonate-rich sediments to 120 meters below seafloor (mbsf) and 2.5 m of underlying basalt. A reentry system was deployed in Hole U1560B to 122.0 mbsf. We then moved to the sites at the western end of the transect on ~61 Ma crust. In Hole U1557D, 10¾ inch casing was deployed to 571.6 mbsf to deepen the 16 inch casing that was deployed during Expedition 390C, and in Hole U1556B, a reentry system was deployed to 284.2 mbsf. The remaining operations time was insufficient to install a reentry system at the originally planned site, Proposed Site SATL-33B. Instead, we cored Hole U1561A (Proposed Site SATL-55A) to 47 mbsf. It is composed of red clay and carbonate ooze overlying 3 m of basalt. The six primary sites of the South Atlantic Transect lie perpendicular to the Mid-Atlantic Ridge on the South American plate, overlying crust ranging in age from 7 to 61 Ma. Basement coring will increase our understanding of how crustal alteration progresses over time across the flanks of a slow/intermediate-spreading ridge and how microorganisms survive in deep subsurface environments. Sediment will be used in paleoceanographic and microbiological studies. 

International Ocean Discovery Program Expedition 382, Iceberg Alley and Subantarctic Ice and Ocean Dynamics, investigated the long-term climate history of Antarctica, seeking to understand how polar ice sheets responded to changes in insolation and atmospheric CO2 in the past and how ice sheet evolution influenced global sea level and vice versa. Five sites (U1534–U1538) were drilled east of the Drake Passage: two sites at 53.2°S at the northern edge of the Scotia Sea and three sites at 57.4°–59.4°S in the southern Scotia Sea. We recovered continuously deposited late Neogene sediments to reconstruct the past history and variability in Antarctic Ice Sheet (AIS) mass loss and associated changes in oceanic and atmospheric circulation. The sites from the southern Scotia Sea (Sites U1536–U1538) will be used to study the Neogene flux of icebergs through “Iceberg Alley,” the main pathway along which icebergs calved from the margin of the AIS travel as they move equatorward into the warmer waters of the Antarctic Circumpolar Current (ACC). In particular, sediments from this area will allow us to assess the magnitude of iceberg flux during key times of AIS evolution, including the following: • The middle Miocene glacial intensification of the East Antarctic Ice Sheet, • The mid-Pliocene warm period, • The late Pliocene glacial expansion of the West Antarctic Ice Sheet, • The mid-Pleistocene transition (MPT), and • The “warm interglacials” and glacial terminations of the last 800 ky. We will use the geochemical provenance of iceberg-rafted detritus and other glacially eroded material to determine regional sources of AIS mass loss. We will also address interhemispheric phasing of ice sheet growth and decay, study the distribution and history of land-based versus marine-based ice sheets around the continent over time, and explore the links between AIS variability and global sea level. By comparing north–south variations across the Scotia Sea between the Pirie Basin (Site U1538) and the Dove Basin (Sites U1536 and U1537), Expedition 382 will also deliver critical information on how climate changes in the Southern Ocean affect ocean circulation through the Drake Passage, meridional overturning in the region, water mass production, ocean–atmosphere CO2 transfer by wind-induced upwelling, sea ice variability, bottom water outflow from the Weddell Sea, Antarctic weathering inputs, and changes in oceanic and atmospheric fronts in the vicinity of the ACC. Comparing changes in dust proxy records between the Scotia Sea and Antarctic ice cores will also provide a detailed reconstruction of changes in the Southern Hemisphere westerlies on millennial and orbital timescales for the last 800 ky. Extending the ocean dust record beyond the last 800 ky will help to evaluate dust-climate couplings since the Pliocene, the potential role of dust in iron fertilization and atmospheric CO2 drawdown during glacials, and whether dust input to Antarctica played a role in the MPT. The principal scientific objective of Subantarctic Front Sites U1534 and U1535 at the northern limit of the Scotia Sea is to reconstruct and understand how intermediate water formation in the southwest Atlantic responds to changes in connectivity between the Atlantic and Pacific basins, the “cold water route.” The Subantarctic Front contourite drift, deposited between 400 and 2000 m water depth on the northern flank of an east–west trending trough off the Chilean continental shelf, is ideally situated to monitor millennial- to orbital-scale variability in the export of Antarctic Intermediate Water beneath the Subantarctic Front. During Expedition 382, we recovered continuously deposited sediments from this drift spanning the late Pleistocene (from ~0.78 Ma to recent) and from the late Pliocene (~3.1–2.6 Ma). These sites are expected to yield a wide array of paleoceanographic records that can be used to interpret past changes in the density structure of the Atlantic sector of the Southern Ocean, track migrations of the Subantarctic Front, and give insights into the role and evolution of the cold water route over significant climate episodes, including the following: • The most recent warm interglacials of the late Pleistocene and • The intensification of Northern Hemisphere glaciation.