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  1. The Pure Shear (PS) crack specimen is widely employed to assess the fracture toughness of soft elastic materials. It serves as a valuable tool for investigating the behavior of crack growth in a steady-state manner following crack initiation. One of its advantages lies in the fact that the energy release rate (J) remains approximately constant for sufficiently long cracks, independent of crack length. Additionally, the PS specimen facilitates the easy evaluation of J for long cracks by means of a tension test conducted on an uncracked sample. However, the lack of a published expression for short cracks currently restricts the usefulness of this specimen. To overcome this limitation, we conducted a series of finite element (FE) simulations utilizing three different constitutive models, namely the neo-Hookean (NH), Arruda-Boyce (AB), and Mooney-Rivlin (MR) models. Our finite element analysis (FEA) encompassed practical crack lengths and strain levels. The results revealed that under a fixed applied displacement, the energy release rate (J) monotonically increases with the crack length for short cracks, reaches a steady-state value when the crack length exceeds the height of the specimen, and subsequently decreases as the crack approaches the end of the specimen. Drawing from these findings, we propose a simple closed-form expression for J that can be applied to most hyper-elastic models and is suitable for all practical crack lengths, particularly short cracks. 
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    Free, publicly-accessible full text available December 1, 2024
  2. An experimental and theoretical study of delayed fracture of polydimethlsiloxane (PDMS) is presented. Previous works have demonstrated that delayed fracture in single edge notch specimens is caused by time dependent damage due to chain scission. Here we study the interactions between damage and the elastic field using different specimens and crack geometries with blunt and sharp cracks. Our experiments show that initial toughness is not well defined, as stable slow crack growth can occur over a range of applied loads. Our experiments demonstrate that there is a universal relation between crack growth rate and applied energy release rate. A model coupling the nonlinear elastic deformation and rate dependent bond scission is proposed and is in good agreement with experimental data. 
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    Free, publicly-accessible full text available December 1, 2024
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  5. A finite strain nonlinear viscoelastic constitutive model is used to study the uniaxial tension behaviour of chemical polyampholyte (PA) gel. This PA gel is cross-linked by chemical and physical bonds. Our constitutive model attempts to capture the time and strain dependent breaking and healing kinetics of physical bonds. We compare model prediction by uniaxial tension, cyclic and relaxation tests. Material parameters in our model are obtained by least squares optimization. These parameters gave fits that are in good agreement with the experiments. 
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