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This study investigates the global distribution of electron temperature enhancement observed by Defense Meteorological Satellite Program F16 satellite and its dependence on the season and solar activity for the solar maximum (2014) and minimum (2018) years during geomagnetic quiet times (maximum per day ap <10). Electron temperature enhancements occurred mainly over the North American‐Atlantic (260°–360°E) and Eurasia (0°–160°E) (Southern Oceania (80°–280°E)) sector in the Northern (Southern) Hemisphere and are prominent in the winter hemispheres and solar maximum year. They have obvious longitude characteristics. Interestingly, they could extend to geomagnetic equatorial regions in the North American‐Atlantic sector from high to low latitudes in the December Solstice, further crossed the magnetic equator, and merged into the Southern Hemisphere in 2014, where the maximum temperature reached ∼3500 K. Our analysis indicates that low‐energy electrons (<100 eV) associated with photoelectron from the conjugate sunlit hemisphere, can contribute to these enhancements. Furthermore, the local geomagnetic declination, magnetic equator position, and terminator position at magnetic conjugate points together can impact the global distribution of photoelectrons of different energies and therefore the electron temperature enhancement distribution. Other processes (including local electron density variation) may play certain roles as well.

 

Long duration electricity storage (LDES) with 10+ hour cycle duration is an economically competitive strategy to accelerate the penetration of renewable energy into the utility market. Unfortunately, none of the available energy storage technologies can meet the LDES requirements in terms of duration and cost. The newly emerged solid-oxide iron–air batteries (SOIABs) with energy-dense solid iron as an energy storage material have inherent advantages for LDES applications. Herein, we report for the first time the LDES capability of SOIABs even at a laboratory scale. We show that SOIABs with an Ir-catalyzed Fe-bed can achieve excellent energy density (625 W h kg −1 ), long cycle duration (12.5 h) and high round-trip efficiency (∼90%) under LDES-related working conditions. Given the excellent low-rate performance and the use of earth-abundant, low-cost Fe as an energy storage material, we conclude that the SOIAB is a well-suited battery technology for LDES applications. 

In the space physics community, processing and combining observational and modeling data from various sources is a demanding task because they often have different formats and use different coordinate systems. The Python package GeospaceLAB has been developed to provide a unified, standardized framework to process data. The package is composed of six core modules, including DataHub as the data manager, Visualization for generating publication quality figures, Express for higher-level interfaces of DataHub and Visualization , SpaceCoordinateSystem for coordinate system transformations, Toolbox for various utilities, and Configuration for preferences. The core modules form a standardized framework for downloading, storing, post-processing and visualizing data in space physics. The object-oriented design makes the core modules of GeospaceLAB easy to modify and extend. So far, GeospaceLAB can process more than twenty kinds of data products from nine databases, and the number will increase in the future. The data sources include, e.g., measurements by EISCAT incoherent scatter radars, DMSP, SWARM, and Grace satellites, OMNI solar wind data, and GITM simulations. In addition, the package provides an interface for the users to add their own data products. Hence, researchers can easily collect, combine, and view multiple kinds of data for their work using GeospaceLAB. Combining data from different sources will lead to a better understanding of the physics of the studied phenomena and may lead to new discoveries. GeospaceLAB is an open source software, which is hosted on GitHub. We welcome everyone in the community to contribute to its future development. 

By employing a chiral bifunctional phosphine ligand, a gold(I)‐catalyzed efficient and highly enantioselective dearomatization of phenols is achieved via versatile metal‐ligand cooperation. The reaction is proven to be remarkably general in scope, permitting substitutions at all four remaining benzene positions, accommodating electron‐withdrawing groups including strongly deactivating nitro, and allowing carbon‐based groups of varying steric bulk includingtert‐butyl at the alkyne terminus. Moreover, besidesN‐(o‐hydroxyphenyl)alkynamides, the corresponding ynoates and ynones are all suitable substrates. Spirocyclohexadienone‐pyrrol‐2‐ones, spirocyclohexadienone‐butenolides, and spirocyclohexadenone‐cyclopentenones are formed in yields up to 99 % and with ee up to 99 %.

 

By employing a chiral bifunctional phosphine ligand, a gold(I)‐catalyzed efficient and highly enantioselective dearomatization of phenols is achieved via versatile metal‐ligand cooperation. The reaction is proven to be remarkably general in scope, permitting substitutions at all four remaining benzene positions, accommodating electron‐withdrawing groups including strongly deactivating nitro, and allowing carbon‐based groups of varying steric bulk includingtert‐butyl at the alkyne terminus. Moreover, besidesN‐(o‐hydroxyphenyl)alkynamides, the corresponding ynoates and ynones are all suitable substrates. Spirocyclohexadienone‐pyrrol‐2‐ones, spirocyclohexadienone‐butenolides, and spirocyclohexadenone‐cyclopentenones are formed in yields up to 99 % and with ee up to 99 %.

 

We study the variations of the topside ionospheric ion density measured by Defense Meteorological Satellite Program satellites during the intense magnetic storm on 7–10 November 2004. It is found for the first time that quasi‐periodic enhancements in the ion density with a period of ∼6 hr occur nearly simultaneously at 0630, 0830, and 0930 local time in the dawn sector during the storm main phase with southward interplanetary magnetic field (IMF). The quasi‐periodic density enhancements extend from the southern subauroral latitudes to the northern subauroral latitudes. In the dusk sector, the topside ion density during the storm main phase is increased at middle latitudes for ∼12 hr but shows decrease or relatively small increase over the magnetic equator, indicating that penetration electric fields dominate the ion density redistribution. Similar quasi‐periodic enhancements in the topside ion density are also observed in the dawn sector during other intense magnetic storms. The solar wind and IMF do not have quasi‐periodic variations in this storm case. Periodic processes in geospace, such as periodic substorms in the magnetosphere, waves and tides in the atmosphere, and traveling ionospheric disturbances, cannot explain the observed periodic enhancements of the ionospheric ion density. We suggest that the magnetosphere‐ionospheric‐thermospheric system may have an intrinsic period of ∼6 hr and that oscillations of the magnetosphere‐ionospheric‐thermospheric system with this period can be excited during intense magnetic storms, although the mechanisms for the generation of the long‐periodic oscillations are not understood.

 

We have used measurements of the Defense Meteorological Satellite Program (DMSP) satellites to study variations of electron temperature in the subauroral ionosphere during the magnetic storm on 17–25 March 2015. This magnetic storm had a long recovery phase of 7 days, and the ionospheric behavior over the entire storm time was seldom investigated. In this study, we find that the electron temperature at subauroral latitudes was continuously enhanced for 8 days, from the storm onset to the end of the recovery phase. The maximum electron temperature during the storm times was 1000–4000 K higher than the maximum electron temperature during quiet times. This long‐lasting enhancement of subauroral electron temperature was attributed to energy transfer among the solar wind, magnetosphere, ring current, plasmasphere, and ionosphere driven by high‐speed solar wind streams and fluctuating interplanetary magnetic field during the entire 8‐day period of the storm. The electron temperature enhancements were quite symmetric in the post‐midnight sector but became strongly asymmetric near dawn between the southern and northern hemispheres. The asymmetric enhancements of electron temperature near dawn may be related to the magnetic declination and the daytime midlatitude trough in the southern hemisphere. Large daily variations of maximum electron temperature in the post‐midnight sector were observed and may be related to the offset between geomagnetic and geographic latitudes. These DMSP observations provide new insight on ionospheric response to intense magnetic storms.

 

We identified a few new storm‐time ionospheric phenomena by analyzing disturbances in topside ion density, electron temperature, and ion temperature at ∼840 km altitude measured by theDefense Meteorological Satellite Programsatellites during the 20 November 2003 magnetic storm. The storm‐time ion density enhancements showed different features at different local times. Longitudinal structures in the enhanced ion density occurred in the morning sector and extended from equatorial regions to middle latitudes. Ion density increase due to enhanced fountain effect was observed in the evening sector and lasted for ∼18 hr. A positive ionospheric storm occurred during the late recovery phase of the storm and was associated with increased atomic oxygen to molecular nitrogen column density ratio. Electron temperature at subauroral latitudes reached 8000 K during the storm, ∼4000 K higher than the quiet‐time temperature. The subauroral temperature enhancement lasted for 2–3 days. Simultaneous enhancements in the ion density, electron temperature, and ion temperature from subauroral to equatorial latitudes occurred in the night‐time ionosphere and lasted for ∼18 hr. A negative correlation between ion density and electron/ion temperature variations occurred in the dusk sector for ∼12 hr. An enhanced ion temperature crest in the winter hemisphere during the magnetic storm lasted for 2 days. A decrease in the ion temperature crest was also observed with an increase of the ion density. These new features in the ionospheric density and temperature, together with the results from previous studies, provide a more comprehensive scenario of the ionospheric response to the superstorm.