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Award ID contains: 1609043

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  1. ; ; ; ; ; (, Chemical Communications)
    Although a wide variety of boron-based “scorpionate” ligands have been implemented, a modular route that offers facile access to different substitution patterns at boron has yet to be developed. Here, we demonstrate new reactivity patterns at the bridgehead positions of a ruthenium tris(pyrid-2-yl)borate complex that allow for facile tuning of steric and electronic properties. 
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  2. ; ; ; (, Molecules)
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