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A fundamental challenge in energy sustainability is efficient utilization of solar energy towards energy‐neutral systems. The current solar cell technologies have been most widely employed to achieve this goal, but are limited to a single‐layer 2D surface. To harvest solar light more efficiently, a multilayer system capable of harvesting solar light in a cuboid through transparent photothermal thin films of iron oxide and a porphyrin compound is developed. Analogous to a multilayer capacitor, an array of transparent, spectral selective, photothermal thin films allows white light to penetrate them, not only collecting photon energy in a 3D space, but generating sufficient heat on each layer with significantly increased total surface area. In this fashion, thermal energy is generated via a multilayer photothermal system that functions as an efficient solar collector, energy converter and generator with high energy density. A solar‐activated thermal energy generator that can produce heat without any power supply and reach a maximum temperature of 76.1 °C is constructed. With a constant incoming white light (0.4 W cm⁻²), the thermal energy generated can be amplified 12‐fold via multilayers. The multilayer system extends another dimension in solar harvesting and paves a new path to energy generation for the energy‐neutral system.

 

To address the critical issues in solar energy, the current research has focused on developing advanced solar harvesting materials that are low cost, lightweight, and environmentally friendly. Among many organic photovoltaics (PVs), the porphyrin compounds exhibit unique structural features that are responsible for strong ultraviolet (UV) and near infrared absorptions and high average visible transmittance, making them ideal candidates for solar-based energy applications. The porphyrin compounds have also been found to exhibit strong photothermal (PT) effects and recently applied for optical thermal insulation of building skins. These structural and optical properties of the porphyrin compounds enable them to function as a PT or a PV device upon sufficient solar harvesting. It is possible to develop a transparent porphyrin thin film with PT- and PV-dual-modality for converting sunlight to either electricity or thermal energy, which can be altered depending on energy consumption needs. A building skin can be engineered into an active device with the PT- and PV-dual modality for large-scale energy harvesting, saving, and generation. This review provides the current experimental results on the PT and PV properties of the porphyrin compounds such as chlorophyll and chlorophyllin. Their PT and PV mechanisms are discussed in correlations to their electronic structures. Also discussed are the synthesis routes, thin film deposition, and potential energy applications of the porphyrin compounds. 

The photothermal experiments on the incident light angle dependence are carried out using simulated solar light on thin films of both iron oxides (Fe3O4 and Fe3O4@Cu2-xS) and porphyrin compounds (chlorophyll and chlorophyllin). Fe3O4 and Fe3O4@Cu2-xS are synthesized using various solution methods that produce mono-dispersed nanoparticles on the order of 10 nm. Chlorophyll is extracted from fresh spinach and chlorophyllin sodium copper is a commercial product. These photothermal (PT) materials are dispersed in polymethyl methacrylate (PMMA) solutions and deposited on glass substrates via spin coating that result in clear and transparent thin films. The iron-oxide based thin films show distinctive absorption spectra; Fe3O4 exhibits a strong peak near UV and gradually decreases into the visible and NIR regions; the absorption of Fe3O4@Cu2-xS is similar in the UV region but shows a broad absorption in the NIR region. Both chlorophyll and chlorophyllin are characterized with absorption peaks near UV and NIR showing a “U”-shaped spectrum, ideally required for efficient solar harvest and high transparency in energy-efficient single-pane window applications. Upon coating of the transparent PT films on the window inner surfaces, solar irradiation induces the photothermal effect, consequently raising the film temperature. In this fashion, the thermal loss through the window can be significantly lowered by reducing the temperature difference between the window inner surface and the room interior, based on a new concept of so-called “optical thermal insulation” (OTI) without any intervention medium, such as air/argon, as required in the glazing technologies. Single-panes are therefore possible to replace double- or triple panes. As OTI is inevitably affected by seasonal and daily sunlight changes, an incident light angle dependence of the photothermal effect is crucial in both thin film and window designs. It is found that the heating curves reach their maxima at small angles of incidence while the photothermal effect is considerably reduced at large angles. This angle dependence is well explained by light reflection by the thin film surface, however, deviated from what is predicted by the Fresnel’s law, attributable to non-ideal surfaces of the substrates. The angle dependence data provides an important reference for OTI that window exposure to sun is greater at winter solstice while that is considerably reduced in the summer. This conclusion indicates much enhanced solar harvesting and heat conversion via optically insulated windows in the winter season, resulting in much lower U-factors. 

ABSTRACT To understand the potential impacts on both thermal performance and condensation risks of using low-e coatings in buildings, especially in the single-pane sector, in this work, parametric numerical analysis in winter is conducted. Three building glazing models, including the single-pane without low-e coatings (SNL), single-pane with exterior low-e coatings (SEL), and single-pane with interior low-e coatings (SIL), are selected and simulated through COMSOL over a range of outdoor temperature and indoor humidity. The temperature of the interior surface of windows, heat flux through windows, winter U-factor of center-of-glass will be obtained and compared. Additionally, a numerical code is developed in R to compute and plot the condensation temperatures of these three models upon the given indoor humidity levels and simulated surface temperatures. The comprehensive analysis of condensation risks on the glazing inner surface of the three models will be conducted. This parametric simulation effort indicates an interesting feature for a single-pane window: while the SIL gives a substantially lower U than the SNL, it also corresponds to an increased condensation risk under certain limits of external temperature and indoor humidity levels. Upon the resultant condensation temperatures and thermal performance analysis, we can conclude the parameters of the windowpane property, coating emissivity and placement, local climate, and building interior thermal settings must be taken into account collectively when it comes to adding low-e coatings to single-pane windows. 

To address critical energy issues in civic structures, we have developed a novel concept of optical thermal insulation (OTI) without relying on a conventional thermal intervention medium, such as air or argon, as often used in conventional window systems. We have synthesized the photothermal (PT) materials, such as the Fe 3 O 4 and Fe 3 O 4 @Cu 2− x S nanoparticles, that exhibit strong UV and near-infrared (NIR) absorptions but with good visible transparency. Upon coating the inner surface of the window glass with a PT film, under solar irradiation, the inner surface temperature rises due to the PT effect. Subsequently, the temperature difference, Δ T , is reduced between the single pane and room interior. This leads to lower the thermal loss through a window, reflected by the U -factor, resulting in considerable energy saving without double- or triple-glazing. Comparing with the Fe 3 O 4 coatings, Fe 3 O 4 @Cu 2− x S is spectrally characterized with a much stronger NIR absorbance, contributing to an increased PT efficiency under simulated solar irradiation (0.1 W/cm 2 ). PT experiments are carried out via both white light and monochromic NIR irradiations (785 nm). The parameters associated with the thermal performance of the PT films are calculated, including PT conversion efficiency, specific absorption rate (SAR), and U -factor. Based on the concept of OTI, we have reached an optimum U -factor of 1.46 W/m 2 K for a single pane, which is satisfactory to the DOE requirement (<1.7 W/m 2 K). 

One of the critical components of energy savings in buildings is thermal insulation, especially for windows in cold climates. The conventional approach mainly relies on a double-pane design. In this study, a new concept of “Green Window” has been designed for single-pane applications that lower the U-factor. The “Green Window” is structurally and simply composed of a thin film window coating of chlorophyll that exhibits pronounced photothermal effect, while remaining highly transparent. We demonstrate a new concept in “thermal insulation” via optical means instead of solely through thermal insulators or spectral selectivity. This concept lifts the dependence on insulating materials making single-pane window highly possible. 

Advances and innovations in materials science and engineering have always played a substantial role in civil engineering, building structural design, and construction. In recent years, extensive effort has been devoted to the applications of stimuli-responsive smart materials and nanostructures in buildings. These smart materials used in the built environment can be defined as those offering specific functional and adaptable properties in response to thermal, optical, structural, and environmental stimuli. Not only do these materials enhance the overall performance of new building construction but also promise safer structures, longer durability of building elements, efficient building energy savings, greater environmental sustainability, and even higher indoor user comfort. Given the increasing imperatives for the above, we have organized this themed special issue that focuses on smart buildings and construction materials. The main aim of this special issue is to encapsulate the current interest and state of research related to the smart materials in building and construction applications, underpinning current and future challenges in building energy, environmental sustainability, and structural safety and durability. 

Windows and glazing systems play an important role in making an energy-efficient home. A portable easy-to-use in-situ measuring system of the window properties using low-cost Arduino platforms and compatible sensors is developed, 3D-printed, and then fabricated in this project and used to measure the parameters including U-factor, Solar Heat Gain Coefficient (SHGC), and Visible Light Transmittance (VT). Comparing resultant output from the developed Arduino sensing and measurements to professional in-situ instruments, we demonstrate that this simple and compact Arduino-based instrument can obtain major window properties with reasonable accuracy. This simple but scalable sensing and measuring approach and Do-It-Yourself (DIY) fabrication workflow could be performed by creative people and even homeowners without needing complex training and building physics knowledge.