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Mechanistic Studies of the Deoxydehydration of Polyols Catalyzed by a Mo(VI) Dioxo(pyridine-2,6-dicarboxylato) Complex

https://doi.org/10.1021/acs.organomet.3c00001

Tran, Randy; Canote, Cody A.; Kilyanek, Stefan M. (June 2023, Organometallics)

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Optimization of electrochemical time of flight measurements for precise determinations of diffusion coefficients over a wide range in various media

https://doi.org/10.1016/j.electacta.2020.136113

Moldenhauer, Jonathan; Sella, Catherine; Moffett, Becca; Baker, Joel; Thouin, Laurent; Amatore, Christian; Kilyanek, Stefan M.; Paul, David W. (June 2020, Electrochimica Acta)
null (Ed.)
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Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview

https://doi.org/10.1098/rsos.191165

DeNike, Kayla A.; Kilyanek, Stefan M. (November 2019, Royal Society Open Science)

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Deoxydehydration of polyols catalyzed by a molybdenum dioxo-complex supported by a dianionic ONO pincer ligand

https://doi.org/10.1039/C9DT03759D

Tran, Randy; Kilyanek, Stefan M. (November 2019, Dalton Transactions)

Deoxydehydration (DODH) is the net reduction of diols and polyols to alkenes or dienes and water. Molybdenum cis -dioxo bis-phenolate ONO complexes were synthesized and have been shown to be active for DODH. Catalysts were screened for activity at 150–190 °C, and appreciable yields of up to 59% were obtained. PPh 3 , Na 2 SO 3 , Zn, C, 3-octanol and 2-propanol were screened as reductants. Additionally, the reactivities of a variety of diols were screened. With ( R , R )-(+)-hydrobenzoin as substrate, DODH occurs via a mechanism where reduction of the Mo catalyst is a result of diol oxidation to form two equivalents of aldehyde. These reactions result in complete conversion and near quantitative yields of trans-stilbene and benzaldehyde.
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Olefin Insertion Reactivity of a (Phosphine-arenesulfonate)Palladium(II) Fluoride Complex

https://doi.org/10.1021/acs.organomet.9b00545

Black, Rebecca E.; Kilyanek, Stefan M.; Reinhart, Erik D.; Jordan, Richard F. (October 2019, Organometallics)

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