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Lemmerz, Lara E. ; Wong, Anthony ; Menard, Gabriel ; Spaniol, Thomas P. ; Okuda, Jun ( , Polyhedron)
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Lemmerz, Lara E. ; Mukherjee, Debabrata ; Spaniol, Thomas P. ; Wong, Anthony ; Ménard, Gabriel ; Maron, Laurent ; Okuda, Jun ( , Chemical Communications)A magnesium hydride cation [(L)MgH] + supported by a macrocyclic ligand (L = Me 4 TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH 2 Mg{N(SiMe 3 ) 2 } 2 ] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
