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Abstract The efficient, 12–14 step (LLS) total synthesis of (−)‐halenaquinone has been achieved. Key steps in the synthetic sequence include: (a) proline sulfonamide‐catalyzed, Yamada–Otani reaction to establish the C6 all‐carbon quaternary stereocenter, (b) multiple, novel palladium‐mediated oxidative cyclizations to introduce the furan moiety, and (c) oxidative Bergman cyclization to form the final quinone ring.more » « less
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El-Mansy, Mohamed; Ghosh, Ankan; Cheong, Paul Ha-Yeon; Carter, Rich (, Synthetic Communications)
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Ghosh, Ankan; Brueckner, Alexander C.; Cheong, Paul Ha-Yeon; Carter, Rich G. (, The Journal of Organic Chemistry)
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Ghosh, Ankan; Carter, Rich G. (, Angewandte Chemie International Edition)
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Li, Xin; Carter, Rich G. (, Organic Letters)
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Li, Xin; Carter, Rich G. (, Organic Letters)
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