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Dipolar order in an amphidynamic crystalline metal–organic framework through reorienting linkers

https://doi.org/10.1038/s41557-020-00618-6

Su, Y.-S.; Lamb, E. S.; Liepuoniute, I.; Chronister, A.; Stanton, A. L.; Guzman, P.; Pérez-Estrada, S.; Chang, T. Y.; Houk, K. N.; Garcia-Garibay, M. A.; et al (March 2021, Nature Chemistry)
null (Ed.)
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Encapsulating N -Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State

https://doi.org/10.1021/jacs.0c11981

Jin, Mingoo; Ando, Rempei; Jellen, Marcus J.; Garcia-Garibay, Miguel A.; Ito, Hajime (January 2021, Journal of the American Chemical Society)
null (Ed.)
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Correlated motion and mechanical gearing in amphidynamic crystalline molecular machines

https://doi.org/10.1039/D0SC04495D

Liepuoniute, Ieva; Jellen, Marcus J.; Garcia-Garibay, Miguel A. (December 2020, Chemical Science)
null (Ed.)
In this review we highlight the recent efforts towards the development of molecular gears with an emphasis on building molecular gears in the solid state and the role that molecular gearing and correlated motions may play in the function of crystalline molecular machines. We discuss current molecular and crystal engineering strategies, challenges associated with engineering correlated motion in crystals, and outline experimental and theoretical tools to explore gearing dynamics while highlighting key advances made to date.
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2D Arrays of Organic Qubit Candidates Embedded into a Pillared-Paddlewheel Metal–Organic Framework

https://doi.org/10.1021/jacs.0c07251

Jellen, Marcus J.; Ayodele, Mayokun J.; Cantu, Annabelle; Forbes, Malcolm D.; Garcia-Garibay, Miguel A. (October 2020, Journal of the American Chemical Society)
null (Ed.)
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Enhanced Rotation by Ground State Destabilization in Amphidynamic Crystals of a Dipolar 2,3-Difluorophenylene Rotator as Established by Solid State ² H NMR and Dielectric Spectroscopy

https://doi.org/10.1021/acs.jpcc.0c05314

Liepuoniute, Ieva; Huynh, Chau Minh; Perez-Estrada, Salvador; Wang, Yangyang; Khan, Saeed; Houk, K. N.; Garcia-Garibay, Miguel A. (July 2020, The Journal of Physical Chemistry C)

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Computational Investigation into Ligand Effects on Correlated Geared Dynamics in Dirhodium Supramolecular Gears—Insights Beyond the NMR Experimental Window

https://doi.org/10.1021/acs.joc.0c01230

Liepuoniute, Ieva; Sanders, Jacob N.; Garcia-Garibay, Miguel A.; Houk, K. N. (July 2020, The Journal of Organic Chemistry)

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Fluorescence Anisotropy Decay of Molecular Rotors with Acene Rotators in Viscous Solution

https://doi.org/10.1021/acs.joc.9b03398

Howe, Morgan E.; Barbour, Nicole A.; Garcia, Ronnie V.; Garcia-Garibay, Miguel A. (June 2020, The Journal of Organic Chemistry)

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Molecular Spur Gears with Triptycene Rotators and a Norbornane-Based Stator

https://doi.org/10.1021/acs.orglett.0c01029

Jiang, Xing; Yang, Song; Jellen, Marcus J.; Houk, K. N.; Garcia-Garibay, Miguel (June 2020, Organic Letters)

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Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals

https://doi.org/10.1002/anie.201909048

Jin, Mingoo; Yamamoto, Sho; Seki, Tomohiro; Ito, Hajime; Garcia‐Garibay, Miguel A. (December 2019, Angewandte Chemie International Edition)

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Thermosalient Amphidynamic Molecular Machines: Motion at the Molecular and Macroscopic Scales

https://doi.org/10.1016/j.matt.2019.06.018

Colin-Molina, Abraham; Karothu, Durga Prasad; Jellen, Marcus J.; Toscano, Rubén A.; Garcia-Garibay, Miguel A.; Naumov, Panče; Rodríguez-Molina, Braulio (October 2019, Matter)

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