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Abstract Structurally complex π‐conjugated polymers hold great promise as key components in sensor and electronic devices; however, their syntheses have not been a trivial task. From a synthetic efficiency perspective, it would be more attractive to access these materials using convenient and efficient methods from simple building blocks. One such synthetic tool, multicomponent polymerization, can accommodate modularity and provide highly efficient syntheses. This feature article outlines several multicomponent polymerization strategies for the synthesis of various π‐conjugated polymers, which are classified based upon how the monomers are aligned during polymerization. Additionally, the challenges and outlooks of this field are highlighted and discussed.
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Abstract A cobaloxime‐catalyzed acceptorless dehydrogenative cyclization ofo‐teraryls was developed. In stark contrast to the established methods such as the Scholl or Mallory reactions, this method does not require any strong acids or oxidants, and shows high atom economy and a broad substrate scope. It operates at near room temperature with light as the source of energy. Acid‐ or oxidant‐sensitive functional groups, such as 4‐methoxyphenyl, unprotected benzyl alcohol, silyl ether, and thiophene groups are tolerated. Remarkably, aryls with electron‐withdrawing groups, and electron‐poor heteroarenes, such as pyridine and pyrimidine, can also react. Preliminary mechanistic study reveals that hydrogen gas is released during the reaction, and both light and the cobalt catalyst are important for the dehydrogenation step.more » « less
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null (Ed.)Graphene nanoribbons (GNRs) – an emerging family of carbon-based semiconductors – can be precisely synthesised from small molecules such as benzene derivatives through bottom-up approaches. This review outlines a summary of the development of bottom-up synthesis of GNRs in liquid phase. The strategies are classified based on edge structures and widths of the materials, which are the crucial factors for properties of GNRs. In addition, views on challenges in the field and the future outlook are also provided.more » « less
