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The critical role of gas fired-plants to compensate renewable generation has increased the operational variability in natural gas networks (GN). Towards developing more reliable and efficient computational tools for GN monitoring, control, and planning, this work considers the task of solving the nonlinear equations governing steady-state flows and pressures in GNs. It is first shown that if the gas flow equations are feasible, they enjoy a unique solution. To the best of our knowledge, this is the first result proving uniqueness of the steady-state gas flow solution over the entire feasible domain of gas injections. To find this solution, we put forth a mixed-integer second-order cone program (MI-SOCP)-based solver relying on a relaxation of the gas flow equations. This relaxation is provably exact under specific network topologies. Unlike existing alternatives, the devised solver does not need proper initialization or knowing the gas flow directions beforehand, and can handle gas networks with compressors. Numerical tests on tree and meshed networks indicate that the relaxation is exact even when the derived conditions are not met.