skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Search for: All records

Award ID contains: 1729538

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Nuclei of ordered materials emerging from the isotropic state usually show a shape topologically equivalent to a sphere; the well-known examples are crystals and nematic liquid crystal droplets. In this work, we explore experimentally and theoretically the toroidal in shape nuclei of columnar lyotropic chromonic liquid crystals coexisting with the isotropic phase. The geometry of these toroids depends strongly on concentrations of the disodium cromoglycate (DSCG) and the crowding agent, polyethylene glycol (PEG). High concentrations of DSCG and PEG result in thick toroids with small central holes, while low concentrations yield thin toroids with wide holes. The multitude of the observed shapes is explained by the balance of bending elasticity and anisotropic interfacial tension. 
    more » « less
  2. Within the framework of the generalised Landau-de Gennes theory, we identify a Q -tensor-based energy that reduces to the four-constant Oseen–Frank energy when it is considered over orientable uniaxial nematic states. Although the commonly considered version of the Landau-de Gennes theory has an elastic contribution that is at most cubic in components of the Q -tensor and their derivatives, the alternative offered here is quartic in these variables. One clear advantage of our approach over the cubic theory is that the associated minimisation problem is well-posed for a significantly wider choice of elastic constants. In particular, this quartic energy can be used to model nematic-to-isotropic phase transitions for highly disparate elastic constants. In addition to proving well-posedness of the proposed version of the Landau-de Gennes theory, we establish a rigorous connection between this theory and its Oseen–Frank counterpart via a Г-convergence argument in the limit of vanishing nematic correlation length. We also prove strong convergence of the associated minimisers. 
    more » « less