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Abstract Temporal variations in lava chemistry at active submarine volcanoes are difficult to decipher due to the challenges of dating their eruptions. Here, we use high-precision measurements of 226Ra-230Th disequilibria in basalts from Kama‘ehuakanaloa (formerly Lō‘ihi) to estimate model ages for recent eruptions of this submarine Hawaiian pre-shield volcano. The ages range from ca. 0 to 2300 yr (excluding two much older samples) with at least five eruptions in the past ∼150 yr. Two snapshots of the magmatic evolution of Kama‘ehuakanaloa (or “Kama‘ehu”) are revealed. First, a long-term transition from alkalic to tholeiitic volcanism was nearly complete by ca. 2 ka. Second, a systematic short-term fluctuation in ratios of incompatible elements (e.g., Th/Yb) for summit lavas occurred on a time scale of ∼1200 yr. This is much longer than the ∼200-yr-long historical cycle in lava chemistry at the neighboring subaerial volcano, Kīlauea. The slower pace of the variation in lava chemistry at Kama‘ehu is most likely controlled by sluggish mantle upwelling on the margin of the Hawaiian plume. 

Many intraplate oceanic islands undergo “rejuvenated” volcanism following the main edifice-building stage. Honolulu features Hawaiʻi’s most recent rejuvenated volcanism. K-Ar dating of Honolulu volcanism suggests that it started at ca. 750 ka and ended at <100 ka. Here, we present new 40Ar/39Ar ages and olivine diffusion modeling from Koko Rift lavas to resolve when the most recent Honolulu eruptions occurred and to evaluate possible mechanisms of rejuvenated volcanism and volcanic hazards. Diffusion modeling of olivine zoning profiles in Koko Rift basalts suggests that magmas were stored in the crust for many months prior to eruption. Six new 40Ar/39Ar ages cluster at 67 ± 2 ka (2σ), which demonstrates that Koko Rift is Hawaiʻi’s youngest known area of rejuvenated volcanism. The timing of Koko Rift eruptions coincides with the pronounced drop in global sea level (∼100 m) during Marine Isotope Stage 4. This major sea-level fall may have triggered the eruptions of Koko Rift magmas that were stored in the crust for months to years at < 15 km depth. The proposed mechanism is similar to that at other volcanic islands, which suggests that changes in global sea level may have significant control on the magnitude and frequency of eruptions at ocean island volcanoes. 

The hydrogen isotope value (δD) of water indigenous to the mantle is masked by the early degassing and recycling of surface water through Earth's history. High 3He/4He ratios in some ocean island basalts, however, provide a clear geochemical signature of deep, primordial mantle that has been isolated within the Earth's interior from melting, degassing, and convective mixing with the upper mantle. Hydrogen isotopes were measured in high 3He/4He submarine basalt glasses from the Southeast Indian Ridge (SEIR) at the Amsterdam–St. Paul (ASP) Plateau (δD = −51 to −90‰, 3He/4He = 7.6 to 14.1 RA) and in submarine glasses from Loihi seamount south of the island of Hawaii (δD = −70 to −90‰, 3He/4He = 22.5 to 27.8 RA). These results highlight two contrasting patterns of δD for high 3He/4He lavas: one trend toward high δD of approximately −50‰, and another converging at δD = −75‰. These same patterns are evident in a global compilation of previously reported δD and 3He/4He results. We suggest that the high δD values result from water recycled during subduction that is carried into the source region of mantle plumes at the core–mantle boundary where it is mixed with primordial mantle, resulting in high δD and moderately high 3He/4He. Conversely, lower δD values of −75‰, in basalts from Loihi seamount and also trace element depleted mid-ocean ridge basalts, imply a primordial Earth hydrogen isotopic value of −75‰ or lower. δD values down to −100‰ also occur in the most trace element-depleted mid-ocean ridge basalts, typically in association with 87Sr/86Sr ratios near 0.703. These lower δD values may be a result of multi-stage melting history of the upper mantle where minor D/H fractionation could be associated with hydrogen retention in nominally anhydrous residual minerals. Collectively, the predominance of δD around −75‰ in the majority of mid-ocean ridge basalts and in high 3He/4He Loihi basalts is consistent with an origin of water on Earth that was dominated by accretion of chondritic material.