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Boronated Cyanometallates

https://doi.org/10.1021/acs.inorgchem.2c03066

McNicholas, Brendon J.; Nie, Cherish; Jose, Anex; Oyala, Paul H.; Takase, Michael K.; Henling, Larry M.; Barth, Alexandra T.; Amaolo, Alessio; Hadt, Ryan G.; Solomon, Edward I.; et al (February 2023, Inorganic Chemistry)

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Photoredox Catalysis Mediated by Tungsten(0) Arylisocyanides in 1,2-Difluorobenzene

https://doi.org/10.1021/acs.inorgchem.1c03767

Barth, Alexandra T.; Morales, Maryann; Winkler, Jay R.; Gray, Harry B. (May 2022, Inorganic Chemistry)

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Excitation-Wavelength-Dependent Photophysics of d ⁸ d ⁸ Di-isocyanide Complexes

https://doi.org/10.1021/acs.inorgchem.1c02645

Pižl, Martin; Hunter, Bryan M.; Sazanovich, Igor V.; Towrie, Michael; Gray, Harry B.; Záliš, Stanislav; Vlček, Antonín (February 2022, Inorganic Chemistry)

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Photoredox Catalysis Mediated by Tungsten(0) Arylisocyanides

https://doi.org/10.1021/jacs.1c07617

Fajardo, Javier; Barth, Alexandra T.; Morales, Maryann; Takase, Michael K.; Winkler, Jay R.; Gray, Harry B. (November 2021, Journal of the American Chemical Society)

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Third-Generation W(CNAr) ₆ Photoreductants (CNAr = Fused-Ring and Alkynyl-Bridged Arylisocyanides)

https://doi.org/10.1021/acs.inorgchem.0c02912

Fajardo, Javier; Schwan, Josef; Kramer, Wesley W.; Takase, Michael K.; Winkler, Jay R.; Gray, Harry B. (March 2021, Inorganic Chemistry)
null (Ed.)
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Cyano-ambivalence: Spectroscopy and photophysics of [Ru(diimine)(CN-BR3)4]2− complexes

https://doi.org/10.1016/j.poly.2020.114692

Ngo, Danh X.; Del Ciello, Sarah A.; McNicholas, Brendon J.; Sanders, Brian C.; Fajardo, Javier; Gray, Harry B.; Winkler, Jay R. (September 2020, Polyhedron)
null (Ed.)
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Electronic Structures, Spectroscopy, and Electrochemistry of [M(diimine)(CN-BR ₃ ) ₄ ] ^2– (M = Fe, Ru; R = Ph, C ₆ F ₅ ) Complexes

https://doi.org/10.1021/acs.inorgchem.0c00632

Ngo, Danh X.; Del Ciello, Sarah A.; Barth, Alexandra T.; Hadt, Ryan G.; Grubbs, Robert H.; Gray, Harry B.; McNicholas, Brendon J. (July 2020, Inorganic Chemistry)
null (Ed.)
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Electronic Structure of Tetracyanonickelate(II)

https://doi.org/10.1021/acs.inorgchem.9b02135

Oppenheim, Julius J.; McNicholas, Brendon J.; Miller, Jayce; Gray, Harry B. (November 2019, Inorganic Chemistry)

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Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions

https://doi.org/10.1021/acs.inorgchem.9b00935

Axtell, Jonathan C.; Messina, Marco S.; Liu, Ji-Yuan; Galaktionova, Daria; Schwan, Josef; Porter, Tyler M.; Savage, Miles D.; Wixtrom, Alex I.; Rheingold, Arnold L.; Kubiak, Clifford P.; et al (June 2019, Inorganic Chemistry)
null (Ed.)
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Tuning the formal potential of ferrocyanide over a 2.1 V range

https://doi.org/10.1039/C8SC04972F

McNicholas, Brendon J.; Grubbs, Robert H.; Winkler, Jay R.; Gray, Harry B.; Despagnet-Ayoub, Emmanuelle (January 2019, Chemical Science)

We report the synthesis and characterization of homoleptic borane adducts of hexacyanoferrate( ii ). Borane coordination blueshifts d–d transitions and CN IR and Raman frequencies. Control over redox properties is established with respect to borane Lewis acidity, reflected in peak anodic potential shifts per borane of +250 mV for BPh 3 and +350 mV for B(C 6 F 5 ) 3 . Electron transfer from [Fe(CN-B(C 6 F 5 ) 3 ) 6 ] 4− to photogenerated [Ru(2,2′-bipyridine) 3 ] 3+ is very rapid, consistent with voltammetry data. Coordination by Lewis acids provides an avenue for selective modification of the electronic structures and electrochemical properties of cyanometalates.
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